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Catena-Poly[[dichloridocopper(II)]-?-4,4'-bis-(benzimidazol-1-yl)biphen-yl].

ABSTRACT: In the title compound, [CuCl(2)(C(26)H(18)N(4))](n), the Cu(II) ion is four-coordinated by two N atoms from two 4,4'-bis-(benzo-imidazol-1-yl)biphenyl ligands and two chloride anions, in a slightly distorted tetra-hedral environment. The biphenyl ligand acts as a linear bidentate ligand, connecting the metal atoms into an infinite chain parallel to [101]. In the biphenyl ligand, the two benzene rings make a dihedral angle of 33.19?(7)°.

SUBMITTER: Xiao DN

PROVIDER: S-EPMC3089309 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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catena-Poly[[dichloridocopper(II)]-μ-4,4'-bis-(benzimidazol-1-yl)biphen-yl].

Xiao Dan-Ni DN Pan Hong-Yan HY Yao Min M Xie Gang G

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

In the title compound, [CuCl(2)(C(26)H(18)N(4))](n), the Cu(II) ion is four-coordinated by two N atoms from two 4,4'-bis-(benzo-imidazol-1-yl)biphenyl ligands and two chloride anions, in a slightly distorted tetra-hedral environment. The biphenyl ligand acts as a linear bidentate ligand, connecting the metal atoms into an infinite chain parallel to [101]. In the biphenyl ligand, the two benzene rings make a dihedral angle of 33.19 (7)°. ...[more]

PMID: 21754264

Similar Datasets

catena-Poly[[dichloridocobalt(II)]-?-4,4'-bis-(benzimidazol-1-yl)biphen-yl].

Project description:In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetra-hedrally coordinated by two chloride ions and two N atoms from 4,4'-bis-(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle between the benzene rings is 34.67?(8)° and the angle between the benene ring and the adjacent benzimidazole ring system is 43.26?(10)°. The bridging ligand links the Co(II) atoms into chains propagating in [[Formula: see text]01].

| S-EPMC3100034 | biostudies-literature

catena-Poly[[dichloridoiron(II)]-μ-4,4''-bis-(benzimidazol-1-yl)-1,1':4',1''-terphen-yl].

Project description:In the title coordination polymer, [FeCl(2)(C(32)H(22)N(4))](n), the Fe(II) atom lies on a crystallographic twofold axis and a distorted FeCl(2)N(2) tetra-hedral coordination geometry arises. The complete ligand is generated by crystallographic twofold symmetry, resulting in an infinite one-dimensional architecture along [101].

| S-EPMC2983580 | biostudies-literature

4,4'-Bis(benzimidazol-1-yl)biphen-yl.

Project description:The mol-ecule of the title compound, C(26)H(18)N(4), resides on a crystallographic inversion centre with a dihedral angle of 44.94 (5)° between the benzimidazole ring system and the benzene ring. The primary hydrogen bond is C-H⋯N and inversion-related pairs of these generate a chain of rings along the c-axis direction; π⋯π stacking involving the benzimidazole groups with inter-planar separations of ca 3.4 Å complete the inter-actions.

| S-EPMC2915210 | biostudies-literature

catena-Poly[[[1,2-bis-(benzimidazol-2-yl)ethane]cadmium(II)]-μ-sebacato].

Project description:In the title compound, [Cd(C(10)H(16)O(4))(C(16)H(14)N(4))](n), the Cd(II) ion is six-coordinated in a distorted octa-hedral geometry by four carboxyl-ate O atoms from two sebacate ligands and two N atoms from the chelating 1,4-bis-(2-benzimidazol-yl)ethanebutane ligand. Neighboring Cd(II) ions are bridged by the sebacate ligands, forming a zigzag polymeric chain structure. The chains are further extended into a three-dimensional supra-molecular structure through inter-molecular N-H⋯O hydrogen bonds.

| S-EPMC2983954 | biostudies-literature

catena-Poly[[dinitratocopper(II)]-?-4,4''-bis-(1H-benzimidazol-1-yl)-1,1':4',1''-terphen-yl].

Project description:In the title one-dimensional coordination polymer, [Cu(NO(3))(2)(C(32)H(22)N(4))](n), the Cu(2+) ion (site symmetry 2) is coordinated by two nitrate O atoms and two N atoms from two 4,4'-bis-(benzoimidazol-1-yl)terphenyl (L) ligands in a distorted cis-CuN(2)O(2) square-planar coordination geometry. An alternative description of the metal coordination geometry, if long Cu-O contacts to the bonded nitrate anions are considered, is an extremely distorted cis-CuN(2)O(4) octa-hedron. The complete L ligand is generated by crystallographic twofold symmetry and connects the metal ions into infinite chains propagating in [10[Formula: see text]]. The dihedral angle between the benzimidazole ring system and the adjacent benzene (B) ring is 51.12?(11)° and the dihedral angle between the B ring and the central ring is 19.45?(13)°.

| S-EPMC3089250 | biostudies-literature

catena-Poly[[bis-(acetato-?O,O')cobalt(II)]-?-4,4'-bis-(benzimidazol-1-yl)biphenyl-?N:N].

Project description:In the title one-dimensional coordination polymer, [Co(C(2)H(3)O(2))(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is coordinated by two O,O'-bidentate acetate ions and two 4,4'-bis-(benzimidazol-1-yl)biphenyl ligands in a distorted cis-CoN(2)O(4) octa-hedral geometry. The bridging ligand, which is completed by crystallographic twofold symmetry, links the Co(II) atoms into [10] chains. Within the ligand, the dihedral angle between the benzene and benzimidazole rings is 48.31?(8)°.

| S-EPMC3011745 | biostudies-literature

catena-Poly[[[diaqua-diformatonickel(II)]-μ-1,4-bis-(1H-benzimidazol-1-yl)benzene] dihydrate].

Project description:In the title one-dimensional coordination polymer, {[Ni(CHO(2))(2)(C(20)H(14)N(4))(H(2)O)(2)]·2H(2)O}(n), the Ni(II) atom lies on a crystallographic inversion centre. It is coordinated by two formate O atoms, two water O atoms and two N atoms from two 1,4-bis-(1H-benzimidazol-1-yl)benzene (bzb) ligands, resulting in a distorted trans-NiN(2)O(4) octa-hedral coordination geometry. The bzb mol-ecule acts as a bridging ligand to connect the metal atoms into a chain propagating in [1[Formula: see text][Formula: see text]]. The dihedral angle between the benzimidazole ring and the central benzene ring in the ligand is 38.16 (9)°. In the crystal, O-H⋯O hydrogen bonds crosslink the chains into (010) sheets.

| S-EPMC3274932 | biostudies-literature

catena-Poly[[bis-(3,5-dicarboxy-benzo-ato)cobalt(II)]-μ-4,4'-bipyridine].

Project description:In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzene-tricarboxylic acid anion and one-half of a 4,4'-bipyridine (4,4'-bipy) mol-ecule, in which two N and two C atoms have site symmetry 2. In the crystal structure, the Co(2+) centre is coordinated by four O atoms from two bidentate carboxyl-ate groups of two anions and two N atoms of two 4,4'-bipy mol-ecules, resulting in infinite chains propagating in [010]. The cobalt coordination is distorted trans-CoO(4)N(2) octa-hedral and inter-chain O-H⋯O hydrogen bonds complete the structure.

| S-EPMC2959783 | biostudies-literature

catena-Poly[[[(2-phenyl-acetato-κO)zinc(II)]bis-[μ-4,4'-(disulfanedi-yl)dipyridine-κN:N']] monohydrate].

Project description:In the title compound, {[Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2)S(2))(2)]·H(2)O}(n), the Zn(II) atom is coordinated by four N atoms from four 4,4'-(disulfanedi-yl)dipyridine (bpds) ligands and two O atoms from two 2-phenyl-acetate anions in a distorted octa-hedral coordination geometry. The two bpds ligands of the same axial chirality bridge Zn(II) atoms, generating repeated rhomboidal chains, which are linked by O-H⋯O hydrogen bonds into a ladder structure.

| S-EPMC3007060 | biostudies-literature

catena-Poly[[[dichloridozinc(II)]-?-1,4-bis-(1H-benzimidazol-2-yl-?N)butane] 1,4-bis-(1H-benzimidazol-2-yl)butane solvate].

Project description:In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl(2)(C(18)H(18)N(4))]·C(18)H(18)N(4)}(n), the tetrahedrally coordinated Zn(II) ions are linked by the N-heterocycle into a linear chain. Another N-heterocycle present is not coordinated to the metal atom but inter-acts with the chain through N-H?N and N-H?Cl hydrogen bonds. The butyl chain of the uncoordinated ligand is disordered over three positions in a 0.511?(4):0.289?(5):0.200?(5) ratio.

| S-EPMC2980004 | biostudies-literature

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