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Catena-Poly[[dichloridocopper(II)]-?-4,4'-bis-(benzimidazol-1-yl)biphen-yl].


ABSTRACT: In the title compound, [CuCl(2)(C(26)H(18)N(4))](n), the Cu(II) ion is four-coordinated by two N atoms from two 4,4'-bis-(benzo-imidazol-1-yl)biphenyl ligands and two chloride anions, in a slightly distorted tetra-hedral environment. The biphenyl ligand acts as a linear bidentate ligand, connecting the metal atoms into an infinite chain parallel to [101]. In the biphenyl ligand, the two benzene rings make a dihedral angle of 33.19?(7)°.

SUBMITTER: Xiao DN 

PROVIDER: S-EPMC3089309 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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catena-Poly[[dichloridocopper(II)]-μ-4,4'-bis-(benzimidazol-1-yl)biphen-yl].

Xiao Dan-Ni DN   Pan Hong-Yan HY   Yao Min M   Xie Gang G  

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5


In the title compound, [CuCl(2)(C(26)H(18)N(4))](n), the Cu(II) ion is four-coordinated by two N atoms from two 4,4'-bis-(benzo-imidazol-1-yl)biphenyl ligands and two chloride anions, in a slightly distorted tetra-hedral environment. The biphenyl ligand acts as a linear bidentate ligand, connecting the metal atoms into an infinite chain parallel to [101]. In the biphenyl ligand, the two benzene rings make a dihedral angle of 33.19 (7)°. ...[more]

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