Unknown

Dataset Information

0

Trans-Dichloridobis[(pyridin-4-yl)boronic acid-?N]palladium(II) dimethyl sulfoxide disolvate.

ABSTRACT: In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd-N and Pd-Cl distances are 2.023?(2) and 2.2977?(7)?Å, respectively, and the average N-Pd-Cl angle is 90°. The dimethyl sulfoxide solvent mol-ecules play a key role in the crystal structure by bridging the complex mol-ecules via O-H?O hydrogen bonds, forming tapes running along the b axis. C-H?O inter-actions also contribute to the cohesion of the crystal.

SUBMITTER: Duong A 

PROVIDER: S-EPMC3089363 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate.

Duong Adam A   Wuest James D JD   Maris Thierry T  

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd-N and Pd-Cl distances are 2.023 (2) and 2.2977 (7) Å, respectively, and the average N-Pd-Cl angle is 90°. The dimethyl sulfoxide solvent mol-ecules play a key role in the crystal structure by bridging the complex mol-ecules via O-H⋯O hydrogen bonds, formin  ...[more]

Similar Datasets

Unknown trans-Dichloridobis(2,4-dimethyl-aniline-?N)palladium(II).
| S-EPMC3344335 | biostudies-literature
Unknown trans-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane}palladium(II).
| S-EPMC3009084 | biostudies-other
Unknown trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II).
| S-EPMC2971166 | biostudies-literature
Unknown trans-Dichloridobis[diphen-yl(thio-phen-2-yl)phosphane-?P]palladium(II).
| S-EPMC3344332 | biostudies-literature
Unknown trans-Dichloridobis[diphen-yl(4-vinyl-phen-yl)phosphane-?P]palladium(II).
| S-EPMC3238597 | biostudies-literature
Unknown trans-Bis(3-hy-droxy-pyridine-?N)diiodidoplatinum(II) dimethyl sulfoxide disolvate.
| S-EPMC3120409 | biostudies-literature
Unknown trans-Dichloridobis(triphenyl-phosphine)palladium(II).
| S-EPMC2961313 | biostudies-literature
Unknown trans-Dichloridobis[dicyclo-hex-yl(2,4,6-trimethyl-phen-yl)phosphane-κP]palladium(II).
| S-EPMC3515096 | biostudies-literature
Unknown Bis[?-N-(pyridin-2-ylmeth-yl)pyridin-3-amine-?(2) N:N']disilver(I) bis-(perchlorate) dimethyl sulfoxide disolvate.
| S-EPMC3884244 | biostudies-literature
Unknown trans-Dichloridobis(triisopropyl-phosphine-?P)palladium(II).
| S-EPMC2961642 | biostudies-literature