Ontology highlight
ABSTRACT:
SUBMITTER: Boralsky LA
PROVIDER: S-EPMC3090038 | biostudies-literature | 2011 Apr
REPOSITORIES: biostudies-literature
Boralsky Luke A LA Marston Dagmara D Grigg R David RD Hershberger John C JC Schomaker Jennifer M JM
Organic letters 20110325 8
The oxidative functionalization of olefins is a common method for the formation of vicinal carbon-heteroatom bonds. However, oxidative methods to transform allenes into synthetic motifs containing three contiguous carbon-heteroatom bonds are much less developed. This paper describes the use of bicyclic methylene aziridines (MAs), prepared via intramolecular allene aziridination, as scaffolds for functionalization of all three allene carbons. ...[more]