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4-{2-[5-(3,5-Difluoro-phen-yl)-2-methyl-thio-phen-3-yl]-3,3,4,4,5,5-hexa-fluoro-cyclo-pent-1-en-1-yl}-1,5-dimethyl-pyrrole-2-carbonitrile.

ABSTRACT: In the title compound, C(23)H(14)F(8)N(2)S, the dihedral angles between the pyrrole and thio-phene groups and the almost planar C-C=C-C unit of the cyclo-pentene ring (r.m.s. deviation = 0.4193?Å) are 43.6?(5) and 50.1?(2)°, respectively. The distance of 3.612?(3)?Å between the potentially reactive C atoms of the two heteroaryl substituents is short enough to enable a photocyclization reaction.

SUBMITTER: Liu G

PROVIDER: S-EPMC3099757 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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4-{2-[5-(3,5-Difluoro-phen-yl)-2-methyl-thio-phen-3-yl]-3,3,4,4,5,5-hexa-fluoro-cyclo-pent-1-en-1-yl}-1,5-dimethyl-pyrrole-2-carbonitrile.

Liu Gang G Wang Xiao-Mei XM Fan Cong-Bin CB

Acta crystallographica. Section E, Structure reports online 20110323 Pt 4

In the title compound, C(23)H(14)F(8)N(2)S, the dihedral angles between the pyrrole and thio-phene groups and the almost planar C-C=C-C unit of the cyclo-pentene ring (r.m.s. deviation = 0.4193 Å) are 43.6 (5) and 50.1 (2)°, respectively. The distance of 3.612 (3) Å between the potentially reactive C atoms of the two heteroaryl substituents is short enough to enable a photocyclization reaction. ...[more]

PMID: 21754207

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