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Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate.

ABSTRACT: In the title compound, [Pd(C(18)H(16)N(3)O)(2)]·2CH(3)OH, the Pd(II) atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent mol-ecules form O-H⋯O hydrogen bonds with the complex. Additional non-classical inter-molecular C-H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

SUBMITTER: Lee HM

PROVIDER: S-EPMC3099926 | biostudies-literature |

REPOSITORIES: biostudies-literature

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1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride.

Project description:In the cation of the title salt, C(19)H(19)N(4)O(2) (+)·Cl(-), the dihedral angles between the imidazole ring and the phenyl rings are 70.39 (8) and 86.26 (9)°. The chloride anion inter-acts with the cation through an N-H⋯Cl hydrogen bond. In the crystal, classical N-H⋯O hydrogen bonds link the cations into chains parallel to the b axis. Non-classical C-H⋯Cl and C-H⋯O hydrogen bonds further connect the chains into a three-dimensional network.

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5,5'-Bis[(1H-imidazol-1-yl)meth-yl]-2,2'-bipyridine methanol disolvate.

Project description:The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5'-bis-(bromo-meth-yl)-2,2'-bipyridine with imidazole. The main mol-ecule lies on an inversion center located at the mid-point of the C-C bond joining the two pyridine rings. The asymmetric unit therefore contains one half-mol-ecule and one methanol solvent mol-ecule. The dihedral angle between the pyridine and imidazole rings is 72.32 (5)°. In the crystal, weak inter-molecular O-H⋯N, C-H⋯N and C-H⋯O hydrogen bonds contribute to the stabilization of the packing.

| S-EPMC3051999 | biostudies-literature

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Project description:In the title compound, [PdBr(2)(C(20)H(17)N(3))(2)]·2CH(3)CN, the Pd atom, which lies on an inversion center, is four-coordinated in a square-planar geometry. The two imidazole rings are coplanar and nearly perpendicular to the plane formed by Pd, the coordinated imidazole C atom and one of the Br atoms, making a dihedral angle of 75.1 (2)°.

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Project description:In the title compound, C(19)H(19)N(4)O(2) (+)·Cl(-)·C(2)H(3)N, the dihedral angle between the two phenyl rings is 69.57?(8)° while the dihedral angles between the imidazole ring and the phenyl rings are 70.61?(7) and 82.11?(7)°. In the crystal, N-H?Cl, C-H?O, C-H?Cl and C-H?N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent mol-ecules into a two-dimensional hydrogen-bonded network parallel to (001); an intra-molecular C-H?O hydrogen bond is also observed.

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1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride dimethyl-formamide monosolvate.

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(1H-Imidazol-4-yl)methanol.

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Project description:The Pd(II) ion in the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent mol-ecules via an N-H⋯N inter-action. The crystal structure is consolidated by inter-molecular C-H⋯S inter-actions.

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1,2-Bis[4-(1H-imidazol-1-yl)benzyl-idene]hydrazine.

Project description:The title compound, C(20)H(16)N(6), is centrosymmetric with the mid-point of the N-N bond located on an inversion center. The imidazole ring is oriented at a dihedral angle of 28.03?(6)° with respect to the attached benzene ring. In the crystal, molecules are linked via C-H?N interactions.

| S-EPMC3379501 | biostudies-literature

Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-?N,S}palladium(II) N,N-dimethyl-formamide disolvate.

Project description:In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethyl-formamide (DMF) solvent mol-ecules via an N-H?O inter-action. In addition, C-H?S inter-actions are observed.

| S-EPMC3050367 | biostudies-literature

trans-Dibromidobis(1-ethyl-3-methyl-imidazol-2-yl-idene)palladium(II).

Project description:The title compound, trans-[PdBr(2)(C(6)H(10)N(2))(2)], was synthesized ionothermally in the ionic liquid solvent 1-ethyl-3-methyl-imidazolium bromide. In the crystal, the Pd(II) atoms are square-planarly coordinated to two Br atoms and two neutral (C(6)H(10)N(2)) ligands. The Pd(II) atom is located on an inversion centre.

| S-EPMC3200790 | biostudies-literature

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