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Trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate.

ABSTRACT: In the title compound, [Pd(C(18)H(16)N(3)O)(2)]·2CH(3)OH, the Pd(II) atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent mol-ecules form O-H⋯O hydrogen bonds with the complex. Additional non-classical inter-molecular C-H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001).

SUBMITTER: Lee HM

PROVIDER: S-EPMC3099926 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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trans-Bis[1-(2-anilino-2-oxoeth-yl)-3-benzyl-1H-imidazol-2-yl]palladium(II) methanol disolvate.

Lee Hon Man HM Chang Yu-Chuan YC

Acta crystallographica. Section E, Structure reports online 20110319 Pt 4

In the title compound, [Pd(C(18)H(16)N(3)O)(2)]·2CH(3)OH, the Pd(II) atom is located on a crystallographic inversion center. It has a square-planar coordination geometry, with the two bidentate ligands coordinated in a trans fashion via the carbene C atom and the amido N atoms. The methanol solvent mol-ecules form O-H⋯O hydrogen bonds with the complex. Additional non-classical inter-molecular C-H⋯O hydrogen bonds link the complexes into a two-dimensional network parallel to (001). ...[more]

PMID: 21753982

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