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Cis-Bis(2,2'-bipyridine-κN,N')dichloridocobalt(II) trihydrate.

ABSTRACT: In the title complex, [CoCl(2)(C(10)H(8)N(2))(2)]·3H(2)O, the Co(II) ion is situated on a twofold rotation axis and exhibits a slightly distorted octa-hedral geometry and is chelated by four N atoms of the two bidentate 2,2'-bipyridine ligands and two Cl(-) ions. The crystal packing is stabilized by hydrogen bonding formed between chloride ions and adjacent water mol-ecules. One of the two independent water molecules in the asymmetric unit is disordered over two sets of sites, each on a twofold rotation axis, in a 0.734 (17):0.269 (17) ratio.

SUBMITTER: Arun Kumar K

PROVIDER: S-EPMC3099996 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis(2,2'-bipyridine-κN,N')chloridocobalt(II) perchlorate.

Project description:In the cation of the title compound, [CoCl(C(10)H(8)N(2))(2)]ClO(4), the Co(II) atom displays a distorted trigonal-bipyramidal coordination geometry. The two pyridine rings in each 2,2'-bipyridine ligand form dihedral angles of 10.75 (12) and 4.28 (13)°. The crystal packing is stabilized by inter-ionic C-H⋯O hydrogen bonds, C-H⋯π inter-actions and aromatic π-π stacking inter-actions, with centroid-centroid distances of 3.616 (7) Å.

| S-EPMC2971918 | biostudies-literature

cis-Aqua-bis(2,2'-bipyridine-κN,N')fluoridochromium(III) bis-(perchlorate) dihydrate.

Project description:The title mixed aqua-fluoride complex, [CrF(C(10)H(8)N(2))(2)(H(2)O)](ClO(4))(2)·2H(2)O, has been synthesized by aqua-tion of the corresponding difluoride complex using lanthan-ide(III) ions as F(-) acceptors. The complex crystallizes with a Cr(III) ion at the center of a distorted octa-hedral coordination polyhedron with a cis arrangement of ligands. The crystal packing shows a hydrogen-bonding pattern involving water mol-ecules, the coordinated F atom and the perchlorate anions.

| S-EPMC2979974 | biostudies-literature

Bis(2,2'-bipyridine-κN,N')(thio-cyanato-κN)copper(II) perchlorate.

Project description:The asymmetric unit of title compound, [Cu(NCS)(C(10)H(8)N(2))(2)]ClO(4), contains a bis-(2,2'-bipyridine)(isothio-cyanato)copper(II) cation and a perchlorate anion. In the cation, the Cu(2+) ion is coordinated by four N atoms from two bidentate 2,2'-bipyridine mol-ecules and an N atom from an isothio-cyanate anion, resulting in a distorted CuN(5) pyramidal configuration. The crystal structure is stabilized by weak inter-molecular C-H⋯O and C-H⋯S hydrogen bonds, and weak π-π inter-actions between 2,2'-bipyridine rings [centroid-centroid distance = 3.908 (4) Å]. The perchlorate counteranion is disordered over two positions in a 0.66:0.34 ratio.

| S-EPMC2969965 | biostudies-literature

Bis(2,2'-bipyridine-κN,N')(nitrato-κO)copper(II) perchlorate.

Project description:In the title compound, [Cu(NO(3))(C(10)H(8)N(2))(2)]ClO(4), the five-coordinated Cu(II) atom has a distorted square-pyramidal CuN(4)O environment; the O atom is in the axial position whereas the N atoms from two bipyridine (bipy) ligands are in the equatorial plane. In the crystal, mol-ecules are assembled by C-H⋯O hydrogen bonding and π-π inter-actions between bipy groups [centroid-centroid distances = 3.7686 (16) and 3.7002 (16) Å] into a three-dimensional network. The nitrite anion is equally disordered over two sets of sites.

| S-EPMC3051949 | biostudies-literature

cis-Bis(2,2'-bipyridine-κ(2)N,N')bis-(pyridin-4-amine-κN(1))ruthenium(II) bis-(hexa-fluoridophosphate) acetonitrile monosolvate.

Project description:In the title complex, [Ru(C(10)H(8)N(2))(2)(C(5)H(6)N(2))(2)](PF(6))(2)·CH(3)CN, the Ru(II) atom is bonded to two α-diimine ligands, viz. 2,2'-bipyridine, in a cis configuration and to two 4-amino-pyridine (4Apy) ligands in the expected distorted octa-hedral configuration. The compound is isostructural with [Ru(C(10)H(8)N(2))(2)(C(5)H(6)N(2))(2)](ClO(4))(2)·CH(3)CN [Duan et al. (1999 ▶). J. Coord. Chem.46, 301-312] and both structures are stabilized by classical hydrogen bonds between 4Apy ligands as donors and counter-ions and acetonitrile solvent mol-ecules as acceptors. Indeed, N-H⋯F inter-actions give rise to an inter-molecularly locked assembly of two centrosymmetric complex mol-ecules and two PF(6) (-) counter-ions, which can be considered as the building units of both crystal architectures. The building blocks are connected to one another through hydrogen bonds between 4Apy and the connecting pieces made up of two centrosymmetric motifs with PF(6) (-) ions and acetonitrile mol-ecules, giving rise to ribbons running parallel to [011]. 2(1)-Screw-axis-related complex mol-ecules and PF(6) (-) counter-ions alternate in helical chains formed along the a axis by means of these contacts.

| S-EPMC3569180 | biostudies-literature

Tetra-aqua-(2,2'-bipyridine-κN,N')manganese(II) di-μ-aqua-bis-[aqua-(2,2'-bipyridine-κN,N')(5-sulfonatoisophthalato-κO)manganate(II)] tetra-hydrate.

Project description:The crystal structure of the title salt, [Mn(C(10)H(8)N(2))(H(2)O)(4)][Mn(2)(C(8)H(3)O(7)S)(2)(C(10)H(8)N(2))(2)(H(2)O)(4)]·4H(2)O, consists of mononuclear manganese(II) cations, dinuclear manganate(II) dianions and uncoordinated water mol-ecules. The dianion is located about an inversion center; the Mn(II) atom is coordinated by a 2,2'-bipyridine ligand, a sulfonatoisophthalate group, a water mol-ecule along with two bridging water mol-ecules in an octa-hedral geometry. The cation lies on a twofold rotation axis; the Mn(II) atom is coordinated by four water mol-ecules and a chelating 2,2'-bipyridine ligand in a distorted octa-hedral geometry. A partially overlapped arrangement between the bipyridine ligands and the aromatic ring of the sulfoisophthalate group of adjacent anions is observed; the distance (3.357 Å) indicates π-π stacking. Hydrogen bonds, with the water mol-ecules serving as hydrogen-bond donors, lead to a three-dimensional network architecture.

| S-EPMC2961927 | biostudies-literature

Bis(2,2'-bipyridine-κN,N')(maleato-κO,O)nickel(II) 7.34-hydrate.

Project description:The title compound, [Ni(C(4)H(2)O(4))(C(10)H(8)N(2))(2)]·7.34H(2)O, was obtained by crystallization from an aqueous ethano-lic reaction mixture containing nickel(II) acetate, maleic acid, bipyridine, sodium hydroxide and ammonia. The asymmetric unit contains one independent complex mol-ecule and 7.34 water mol-ecules occupying eight crystallographically independent positions. Two of these water molecules are disordered. The nickel(II) atom is coordinated in a distorted octa-hedral geometry by two O atoms from one carboxyl-ate group of the maleato ligand and by four N atoms from two 2,2'-bipyridine (bipy) ligands. The water mol-ecules, along with the O atoms of the uncoordinated carboxyl-ate group, form an extended hydro-philic three-dimensional hydrogen-bonded system with large cavities in which the hydro-phobic bipy ligands are located. One H atom of the maleate ligand is involved in a weak hydrogen bond of the C-H⋯O type. Stacking inter-actions between the pyridyl rings of the bipy ligands [centroid-centroid distance = 3.549 (15) Å] lead to the formation of pairs of complex mol-ecules.

| S-EPMC2960002 | biostudies-literature

cis-Bis(acetonitrile-?N)bis-(2,2'-bipyridine-?N,N')ruthenium(II) tetra-fluoridoborate.

Project description:In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa-hedral geometry by the N atoms of the two 2,2'-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol-ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86?(12) and 10.12?(14)°. In the crystal, the cations and anions are linked by C-H?F hydrogen bonds into a three-dimensional network.

| S-EPMC3254331 | biostudies-literature

Bis(2,2'-bipyridine-κN,N')(3,5-dinitro-2-oxidobenzoato-κO,O)cobalt(II).

Project description:In the title compound, [Co(C(7)H(2)N(2)O(7))(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by four N atoms from two 2,2'-bipyridine ligands and two O atoms from a 3,5-dinitro-2-oxidobenzoate ligand, displaying a distorted octa-hedral coordination geometry. The crystal structure involves C-H⋯O hydrogen bonds between the 2,2'-bipyridine ligands and the carboxyl-ate and NO(2) groups of the 3,5-dinitro-2-oxidobenzoate ligand.

| S-EPMC2967915 | biostudies-literature

Bis[μ-1,1'-methyl-enebis(1H-imidazole)-κN:N]bis-[dichloridocobalt(II)].

Project description:The title compound, [Co(2)Cl(4)(C(7)H(8)N(4))(2)], contains a dinuclear complex molecule in which each Co(II) atom is tetra-hedrally coordinated by two N atoms and two chloride ions. The 1,1'-methyl-enebis(1H-imidazole) ligands adopt a bis-monodentate bridging mode linking two Co(II) atoms.

| S-EPMC3099993 | biostudies-literature

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