Unknown

Dataset Information

0

(E)-3-(8-Benz-yloxy-2,3-dihydro-1,4-benzodioxin-6-yl)-1-[2-hy-droxy-4,6-bis-(meth-oxy-meth-oxy)phen-yl]prop-2-en-1-one.

ABSTRACT: In the title mol-ecule, C(28)H(28)O(9), the phenol and the benzene rings adjacent to the ?,?-unsaturated ketone unit are inclined at 9.15?(13)° to each other. The terminal phenyl ring is oriented with respect to the phenol ring at a dihedral angle of 85.88?(13)°. In the crystal, the methyl-ene C atoms of the dihydro-dioxine ring are disordered over two sites with an occupancy ratio of 0.463?(18):0.537?(18), and both disordered components of the dihydro-dioxine ring adopt twisted-chair conformations. An intra-molecular O-H?O hydrogen bond and weak inter-molecular C-H?O hydrogen bonds are present in the crystal structure.

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC3100013 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(E)-3-(8-Benz-yloxy-2,3-dihydro-1,4-benzodioxin-6-yl)-1-[2-hy-droxy-4,6-bis-(meth-oxy-meth-oxy)phen-yl]prop-2-en-1-one.

Zhang Yu Y   Zhang Yi-Nan YN   Liu Ming-Ming MM   Ryu Kum-Chol KC   Ye De-Yong DY  

Acta crystallographica. Section E, Structure reports online 20110319 Pt 4

In the title mol-ecule, C(28)H(28)O(9), the phenol and the benzene rings adjacent to the α,β-unsaturated ketone unit are inclined at 9.15 (13)° to each other. The terminal phenyl ring is oriented with respect to the phenol ring at a dihedral angle of 85.88 (13)°. In the crystal, the methyl-ene C atoms of the dihydro-dioxine ring are disordered over two sites with an occupancy ratio of 0.463 (18):0.537 (18), and both disordered components of the dihydro-dioxine ring adopt twisted-chair conformati  ...[more]

Similar Datasets

Unknown (E)-1-[2-Hy-droxy-4,6-bis-(meth-oxy-meth-oxy)phen-yl]-3-[3-meth-oxy-4-(meth-oxy-meth-oxy)phen-yl]prop-2-en-1-one.
| S-EPMC3247344 | biostudies-literature
Unknown (E)-1-[2-Hy-droxy-4,6-bis-(meth-oxy-meth-oxy)phen-yl]-3-phenyl-prop-2-en-1-one.
| S-EPMC3648248 | biostudies-literature
Unknown (2E)-3-[3-(Benz-yloxy)phen-yl]-1-(2-hy-droxy-phen-yl)prop-2-en-1-one.
| S-EPMC3120523 | biostudies-literature
Unknown (E)-1-(2-Hy-droxy-4,6-dimeth-oxy-phen-yl)-3-(4-meth-oxy-phen-yl)prop-2-en-1-one from Kaempferia rotunda Val.
| S-EPMC3009218 | biostudies-literature
Unknown 1-[4-(Prop-2-en-1-yl-oxy)benz-yl]-2-[4-(prop-2-en-1-yl-oxy)phen-yl]-1H-benzimidazole.
| S-EPMC3588921 | biostudies-literature
Unknown (E)-1-(2-Hy-droxy-6-meth-oxy-phen-yl)-3-(2,4,6-tri-meth-oxy-phen-yl)prop-2-en-1-one.
| S-EPMC3885064 | biostudies-literature
Unknown 1-Benz-yloxy-2,5-bis-(chloro-meth-yl)-4-meth-oxy-benzene.
| S-EPMC3414275 | biostudies-literature
Unknown 2-{[(2-Hy-droxy-3,5-dimethyl-benz-yl)(meth-yl)amino]-meth-yl}-4,6-dimethyl-phenol.
| S-EPMC3379400 | biostudies-literature
Unknown tert-Butyl N-(4-hy-droxy-benz-yl)-N-[4-(prop-2-yn-yloxy)benz-yl]carbamate.
| S-EPMC3201299 | biostudies-literature
Unknown (E)-Benz-yl(4-{[1-(prop-2-en-1-yl)-1H-1,2,3-triazol-4-yl]meth-oxy}benzyl-idene)amine.
| S-EPMC3998458 | biostudies-literature