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Poly[(?-2-hy-droxy-3,5-dinitro-benzoato)rubidium].

ABSTRACT: The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(7))](n), comprises an Rb(+) cation and a 3,5-dinitro-salicylate ligand. The Rb(+) cation is 10-coordinated by O atoms from eight 3,5-dinitro-salicylate anions and is linked by three ?(2)-O atoms, forming a zigzag chain along the b-axis direction, which is further linked by the phenyl groups, giving the three-dimensional framework. The crystal structure involves intra-anionic O-H?O hydrogen bonds and strong ?-? stacking inter-actions [centroid-centroid distance = 3.6755?(7)?Å].

SUBMITTER: Meng Y 

PROVIDER: S-EPMC3100035 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Poly[(μ-2-hy-droxy-3,5-dinitro-benzoato)rubidium].

Meng Yan Y  

Acta crystallographica. Section E, Structure reports online 20110315 Pt 4

The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(7))](n), comprises an Rb(+) cation and a 3,5-dinitro-salicylate ligand. The Rb(+) cation is 10-coordinated by O atoms from eight 3,5-dinitro-salicylate anions and is linked by three μ(2)-O atoms, forming a zigzag chain along the b-axis direction, which is further linked by the phenyl groups, giving the three-dimensional framework. The crystal structure involves intra-anionic O-H⋯O hydrogen bonds and strong π-π stacking inter-actions [c  ...[more]

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