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(Benzene-carbothio-amide-?S)-penta-carbonyl-tungsten(0).

ABSTRACT: The asymmetric unit of the title complex, [W(C(7)H(7)NS)(CO)(5)], comprises two independent mol-ecules. In each, the W atom is coordinated by five CO groups and the S atom of the benzencarbothioamide ligand in a distorted octa-hedral geometry. The crystal packing can be described as undulating layers of W(CO)(5) and benzene-carbothio-amide parallel to (001). In the crystal, components are linked via inter-molecular N-H?O and C-H?O hydrogen bonds to form a dimeric chains along the [010] direction. Intra-molecular N-H?C inter-actions are also observed.

SUBMITTER: Merniz S 

PROVIDER: S-EPMC3100038 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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(Benzene-carbothio-amide-κS)-penta-carbonyl-tungsten(0).

Merniz Salah S   Mokhtari Mahiedine M   Bouacida Sofiane S   Ouahab Lahcène L   Mousser Abdelhamid A  

Acta crystallographica. Section E, Structure reports online 20110312 Pt 4

The asymmetric unit of the title complex, [W(C(7)H(7)NS)(CO)(5)], comprises two independent mol-ecules. In each, the W atom is coordinated by five CO groups and the S atom of the benzencarbothioamide ligand in a distorted octa-hedral geometry. The crystal packing can be described as undulating layers of W(CO)(5) and benzene-carbothio-amide parallel to (001). In the crystal, components are linked via inter-molecular N-H⋯O and C-H⋯O hydrogen bonds to form a dimeric chains along the [010] direction  ...[more]

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