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(S)-4-(2-Chloro-propan-2-yl)-1-(2,2,2-trichloro-eth-yl)cyclo-hexene.


ABSTRACT: The title compound, C(11)H(16)Cl(4), was synthesized by the reaction of (1S)-?-pinene with triethyl-amine in the presence of ZnCl(2). The cyclo-hexene ring assumes a half-boat conformation. The crystal packing is governed only by van der Waals inter-actions. The structure, which has been refined in P2(1), presents a striking P2(1)/m pseudosymmetry.

SUBMITTER: Boualy B 

PROVIDER: S-EPMC3100074 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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(S)-4-(2-Chloro-propan-2-yl)-1-(2,2,2-trichloro-eth-yl)cyclo-hexene.

Boualy Brahim B   Harrad Mohamed Anoir MA   Firdoussi Larbi El LE   Ali Mustapha Ait MA   Rizzoli Corrado C  

Acta crystallographica. Section E, Structure reports online 20110323 Pt 4


The title compound, C(11)H(16)Cl(4), was synthesized by the reaction of (1S)-β-pinene with triethyl-amine in the presence of ZnCl(2). The cyclo-hexene ring assumes a half-boat conformation. The crystal packing is governed only by van der Waals inter-actions. The structure, which has been refined in P2(1), presents a striking P2(1)/m pseudosymmetry. ...[more]

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