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Enantioselective dichlorination of allylic alcohols.

ABSTRACT: The development of an enantioselective allylic alcohol dichlorination catalyzed by dimeric cinchona alkaloid derivatives and employing aryl iododichlorides as chlorine sources is reported. Reaction optimization, exploration of the substrate scope, and a model for stereoinduction are presented.

SUBMITTER: Nicolaou KC 

PROVIDER: S-EPMC3107004 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Enantioselective dichlorination of allylic alcohols.

Nicolaou K C KC   Simmons Nicholas L NL   Ying Yongcheng Y   Heretsch Philipp M PM   Chen Jason S JS  

Journal of the American Chemical Society 20110510 21

The development of an enantioselective allylic alcohol dichlorination catalyzed by dimeric cinchona alkaloid derivatives and employing aryl iododichlorides as chlorine sources is reported. Reaction optimization, exploration of the substrate scope, and a model for stereoinduction are presented. ...[more]

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