Ontology highlight
ABSTRACT:
SUBMITTER: Riedel PJ
PROVIDER: S-EPMC3108847 | biostudies-literature | 2011 May
REPOSITORIES: biostudies-literature
Inorganic chemistry communications 20110501 5
Manganese(II) chloride reacts with trimethylsilyl triflate (TMS(OTf) where OTf = (-)OSO(2)CF(3)) in a 1:1 mixture of acetonitrile and tetrahydrofuran, and after recrystallization affords the linear coordination polymer [Mn(II)(CH(3)CN)(2)(OTf)(2)](n). Each distorted octahedral manganese(II) center in the polymeric chain has trans-acetonitriles and the remaining equatorial coordination positions are occupied by the bridging triflate anions. Dissolving [Mn(II)(CH(3)CN)(2)(OTf)(2)](n) in equal volu ...[more]