Unknown

Dataset Information

0

Synthesis of benzocycloheptanones through coupling of ?,?-unsaturated chromium carbene complexes and 2-alkynylbenzoyl derivatives.


ABSTRACT: The coupling of pentenylcarbene complexes and 2-alkynylbenzoyl derivatives affords naphthocycloheptanones in a single step involving simultaneous construction of both the seven-membered ring and one of the aromatic rings. Aryl tethered systems undergo intramolecular cyclopropanation.

SUBMITTER: Patti RK 

PROVIDER: S-EPMC3109730 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

altmetric image

Publications

Synthesis of benzocycloheptanones through coupling of δ,ε-unsaturated chromium carbene complexes and 2-alkynylbenzoyl derivatives.

Patti Rajesh Kumar RK   Waynant Kristopher V KV   Herndon James W JW  

Organic letters 20110509 11


The coupling of pentenylcarbene complexes and 2-alkynylbenzoyl derivatives affords naphthocycloheptanones in a single step involving simultaneous construction of both the seven-membered ring and one of the aromatic rings. Aryl tethered systems undergo intramolecular cyclopropanation. ...[more]

Similar Datasets

| S-EPMC2920532 | biostudies-literature
| S-EPMC2034294 | biostudies-literature
| S-EPMC2427052 | biostudies-literature
| S-EPMC11292013 | biostudies-literature
| S-EPMC5619673 | biostudies-literature
| S-EPMC11348387 | biostudies-literature
| S-EPMC3002078 | biostudies-literature
| S-EPMC2598427 | biostudies-literature
| S-EPMC8587840 | biostudies-literature
| S-EPMC3083066 | biostudies-literature