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Bis(2-methyl-benzoato-?O,O')(1,10'-phenanthroline-?N,N')copper(II).

ABSTRACT: In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octa-hedral coordination geometry, chelated by two N atoms from the 1,10'-phenanthroline ligand and four O atoms from two 2-methyl-benzoate anions. A significant Jahn-Teller distortion is observed with two axial Cu-O distances significantly longer than those in the equatorial CuO(2)N(2) plane. In the crystal, ?-? stacking inter-actions, with centroid-centroid distances of 3.547?(3) or 3.728?(3)?Å between the phenanthroline rings, form layers parallel to (011).

SUBMITTER: Ni SL

PROVIDER: S-EPMC3120328 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Bis(2-methyl-benzoato-κO,O')(1,10'-phenanthroline-κN,N')copper(II).

Ni Sheng-Liang SL Zhou Feng F Qi Jin-Li JL

Acta crystallographica. Section E, Structure reports online 20110520 Pt 6

In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octa-hedral coordination geometry, chelated by two N atoms from the 1,10'-phenanthroline ligand and four O atoms from two 2-methyl-benzoate anions. A significant Jahn-Teller distortion is observed with two axial Cu-O distances significantly longer than those in the equatorial CuO(2)N(2) plane. In the crystal, π-π stacking inter-actions, with centroid-centroid distances of 3.547 (3) or 3.728 (3) Å bet ...[more]

PMID: 21754662

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