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(Z)-N-(2-Chloro-benzyl-idene)aniline N-oxide.

ABSTRACT: In the title compound, C(13)H(10)ClNO, the central C-N bond has considerable double-bond character and the N-O bond indicates a formal negative charge on the O atom. The mol-ecule is stabilized by an intra-molecular C-H?O hydrogen bond. The geometry about the C=N bond is Z [C-C-N-O torsion angle = -4.2?(3)°] and the phenyl and benzene rings are trans-oriented around the C=N bond. The phenyl and benzene rings make a dihedral angle of 56.99?(2)°.

SUBMITTER: Fu Y 

PROVIDER: S-EPMC3120351 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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(Z)-N-(2-Chloro-benzyl-idene)aniline N-oxide.

Fu Ying Y   Liu Yanhua Y   Yang Yanshou Y   Chen Yaojuan Y  

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title compound, C(13)H(10)ClNO, the central C-N bond has considerable double-bond character and the N-O bond indicates a formal negative charge on the O atom. The mol-ecule is stabilized by an intra-molecular C-H⋯O hydrogen bond. The geometry about the C=N bond is Z [C-C-N-O torsion angle = -4.2 (3)°] and the phenyl and benzene rings are trans-oriented around the C=N bond. The phenyl and benzene rings make a dihedral angle of 56.99 (2)°. ...[more]

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