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Bis(diethyl-enetriamine)-cobalt(III) hexa-chloridoindate(III).

ABSTRACT: The title compound, [Co(C(4)H(13)N(3))(2)][InCl(6)], was synthesized under hydro-thermal conditions. In the cation, the Co-N bond lengths lie in the range 1.967?(2)-1.9684?(15)?Å. In the anion, the In(III) atom is coordinated by six Cl atoms resulting in a slightly distorted octa-hedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N-H?Cl hydrogen bonds between cations and anions consolidate the crystal packing.

SUBMITTER: Wu Q 

PROVIDER: S-EPMC3120378 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Bis(diethyl-enetriamine)-cobalt(III) hexa-chloridoindate(III).

Wu Qihui Q   Chen Shangwen S   Zhang Cailing C   Zhi Xia X   Chen Zelin Z  

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The title compound, [Co(C(4)H(13)N(3))(2)][InCl(6)], was synthesized under hydro-thermal conditions. In the cation, the Co-N bond lengths lie in the range 1.967 (2)-1.9684 (15) Å. In the anion, the In(III) atom is coordinated by six Cl atoms resulting in a slightly distorted octa-hedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N-H⋯Cl hydrogen bonds between cations and anions consolidat  ...[more]

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