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Poly[dinitrato[?(3)-2,4,6-tris-(4-pyrid-yl)-1,3,5-triazine]cobalt(II)].

ABSTRACT: The solvothermal reaction of Co(NO(3))(2) and 2,4,6-tris(4-pyridyl)-1,3,5-triazine in dimethyl-formamide/ethanol mixed solvent afforded the title coordination polymer, [Co(NO(3))(2)(C(18)H(12)N(6))](n), in which the Co(II) atom is seven-coordinated by pyridyl groups of three different ligands and two chelating nitrate anions. The complex displays a nano-sized porous metal-organic framework that belongs to a (10,3) topological network.

SUBMITTER: Wang YP 

PROVIDER: S-EPMC3120381 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Poly[dinitrato[μ(3)-2,4,6-tris-(4-pyrid-yl)-1,3,5-triazine]cobalt(II)].

Wang Ya-Ping YP   Zhang Ning N   He Xiang X   Shao Min M   Li Ming-Xing MX  

Acta crystallographica. Section E, Structure reports online 20110514 Pt 6

The solvothermal reaction of Co(NO(3))(2) and 2,4,6-tris(4-pyridyl)-1,3,5-triazine in dimethyl-formamide/ethanol mixed solvent afforded the title coordination polymer, [Co(NO(3))(2)(C(18)H(12)N(6))](n), in which the Co(II) atom is seven-coordinated by pyridyl groups of three different ligands and two chelating nitrate anions. The complex displays a nano-sized porous metal-organic framework that belongs to a (10,3) topological network. ...[more]

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