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Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O'}(formato-?O)manganese(III) dihydrate.

ABSTRACT: The Mn(III) atom in the title complex, [Mn(C(18)H(18)N(2)O(4))(CHO(2))(H(2)O)]·2H(2)O, is O,N,N',O'-chelated by the deproton-ated Schiff base; the four chelating atoms form an approximate square, with the O atoms of the water mol-ecule and the formate ion in axial positions above and below the square plane. Two metal-bearing mol-ecules are linked by an O-H(water)?O hydrogen bond about a center of inversion, generating a hydrogen-bonded dinuclear species; adjacent dinuclear units are linked through the lattice water mol-ecules, forming a three-dimensional network.

SUBMITTER: Lee SM

PROVIDER: S-EPMC3120422 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}(formato-κO)manganese(III) dihydrate.

Lee See Mun SM Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110514 Pt 6

The Mn(III) atom in the title complex, [Mn(C(18)H(18)N(2)O(4))(CHO(2))(H(2)O)]·2H(2)O, is O,N,N',O'-chelated by the deproton-ated Schiff base; the four chelating atoms form an approximate square, with the O atoms of the water mol-ecule and the formate ion in axial positions above and below the square plane. Two metal-bearing mol-ecules are linked by an O-H(water)⋯O hydrogen bond about a center of inversion, generating a hydrogen-bonded dinuclear species; adjacent dinuclear units are linked throu ...[more]

PMID: 21754637

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