Ontology highlight
ABSTRACT:
SUBMITTER: Lee SM
PROVIDER: S-EPMC3120422 | biostudies-literature | 2011 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20110514 Pt 6
The Mn(III) atom in the title complex, [Mn(C(18)H(18)N(2)O(4))(CHO(2))(H(2)O)]·2H(2)O, is O,N,N',O'-chelated by the deproton-ated Schiff base; the four chelating atoms form an approximate square, with the O atoms of the water mol-ecule and the formate ion in axial positions above and below the square plane. Two metal-bearing mol-ecules are linked by an O-H(water)⋯O hydrogen bond about a center of inversion, generating a hydrogen-bonded dinuclear species; adjacent dinuclear units are linked throu ...[more]