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1-Benzyl-3,5-bis-(4-methyl-benzyl-idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate.

ABSTRACT: In the title solvated mol-ecular salt, C(28)H(28)NO(+)·Cl(-)·C(2)H(4)O(2), the central piperidinium ring of the cation adopts an envelope conformation with the N atom displaced by 0.798?(2)?Å from the mean plane of the five C atoms. In the crystal, the components are linked by N-H?Cl and O-H?Cl hydrogen bonds into trimeric assemblies. C-H?Cl and C-H?? inter-actions further consolidate the packing.

SUBMITTER: Sun JF

PROVIDER: S-EPMC3120477 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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1-Benzyl-3,5-bis-(4-methyl-benzyl-idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate.

Sun Ju-Feng JF Xing Juan J Han Jing-Tian JT

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title solvated mol-ecular salt, C(28)H(28)NO(+)·Cl(-)·C(2)H(4)O(2), the central piperidinium ring of the cation adopts an envelope conformation with the N atom displaced by 0.798 (2) Å from the mean plane of the five C atoms. In the crystal, the components are linked by N-H⋯Cl and O-H⋯Cl hydrogen bonds into trimeric assemblies. C-H⋯Cl and C-H⋯π inter-actions further consolidate the packing. ...[more]

PMID: 21754744

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