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5-Fluoro-3-(2-phenyl-hydrazinyl-idene)indolin-2-one.

ABSTRACT: In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenyl-hydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007?Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09?(9)°. The mol-ecular structure is stabilized by a strong intra-molecular N-H?O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structure features inter-molecular N-H?O inter-actions.

SUBMITTER: Wei WB

PROVIDER: S-EPMC3120488 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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5-Fluoro-3-(2-phenyl-hydrazinyl-idene)indolin-2-one.

Wei Wen-Bin WB Tian Shuo S Shen Hong H Sun Jie J Wang Hai-Bo HB

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenyl-hydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09 (9)°. The mol-ecular structure is stabilized by a strong intra-molecular N-H⋯O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structur ...[more]

PMID: 21754700

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