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Methyl c-1-cyano-t-2-methyl-sulfonyl-3-phenyl-cyclo-propane-carboxyl-ate.

ABSTRACT: The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti-omers. Short intra-molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C?O = 2.881?(1), 2.882?(1) and 2.686?(1) Å], indicating the possibility of donor-acceptor inter-actions between these groups. The dihedral angle between the phenyl and cyclopropyl rings is 79.3?(1)°.

SUBMITTER: Vasin VA

PROVIDER: S-EPMC3120552 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Methyl c-1-cyano-t-2-methyl-sulfonyl-3-phenyl-cyclo-propane-carboxyl-ate.

Vasin Victor A VA Bolusheva Irina Yu IY Neverov Vyacheslav A VA Somov Nikolai V NV

Acta crystallographica. Section E, Structure reports online 20110525 Pt 6

The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti-omers. Short intra-molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C⋯O = 2.881 (1), 2.882 (1) and 2.686 (1) Å], indicating the possibility of donor-acceptor inter-actions between these groups. The dihedral angle between the phenyl and cyclopropyl rings is 79.3 (1)°. ...[more]

PMID: 21754871

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