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(E)-3-[4-(Dimethyl-amino)-phen-yl]-1-(2-methyl-4-phenyl-quinolin-3-yl)prop-2-en-1-one 0.7-hydrate.


ABSTRACT: In the title compound, C(27)H(24)N(2)O·0.7H(2)O, the quinoline ring system is approximately planar, with a maximum deviation of 0.011?(1)?Å, and forms dihedral angles of 74.70?(4) and 80.14?(4)° with the phenyl and benzene rings, respectively. In the crystal, the mol-ecules are linked to the water mol-ecules via inter-molecular O-H?N hydrogen bonds and further stabilized by C-H?? inter-actions involving the centroid of the benzene ring of the quinoline group. This benzene ring is observed to form a ?-? inter-action with an adjacent pyridine ring [centroid-centroid distance = 3.7120?(6)?Å].

SUBMITTER: Loh WS 

PROVIDER: S-EPMC3120557 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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(E)-3-[4-(Dimethyl-amino)-phen-yl]-1-(2-methyl-4-phenyl-quinolin-3-yl)prop-2-en-1-one 0.7-hydrate.

Loh Wan-Sin WS   Fun Hoong-Kun HK   Sarveswari S S   Vijayakumar V V   Prasath R R  

Acta crystallographica. Section E, Structure reports online 20110525 Pt 6


In the title compound, C(27)H(24)N(2)O·0.7H(2)O, the quinoline ring system is approximately planar, with a maximum deviation of 0.011 (1) Å, and forms dihedral angles of 74.70 (4) and 80.14 (4)° with the phenyl and benzene rings, respectively. In the crystal, the mol-ecules are linked to the water mol-ecules via inter-molecular O-H⋯N hydrogen bonds and further stabilized by C-H⋯π inter-actions involving the centroid of the benzene ring of the quinoline group. This benzene ring is observed to for  ...[more]

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