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2-{(1R,2R)-2-[Bis(4-methyl-benz-yl)amino]-cyclo-hex-yl}isoindoline-1,3-dione.

ABSTRACT: In the title mol-ecule, C(30)H(32)N(2)O(2), the two tolyl rings form dihedral angles of 65.8?(1) and 6.6?(1)° with the isoindole-1,3-dione mean plane. The cyclo-hexane ring adopts a chair conformation.

SUBMITTER: Li C

PROVIDER: S-EPMC3120613 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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2-{(1R,2R)-2-[Bis(4-methyl-benz-yl)amino]-cyclo-hex-yl}isoindoline-1,3-dione.

Li Chao C Fu Xiang-Kai XK Wu Chuan-Long CL Huang Jing J

Acta crystallographica. Section E, Structure reports online 20110520 Pt 6

In the title mol-ecule, C(30)H(32)N(2)O(2), the two tolyl rings form dihedral angles of 65.8 (1) and 6.6 (1)° with the isoindole-1,3-dione mean plane. The cyclo-hexane ring adopts a chair conformation. ...[more]

PMID: 21754852

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Project description:In the structure of the title compound, C46H37N3O4S, the planes of the two isoindoline units make a dihedral angle of 77.86?(3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56?(4) and 3.74?(9)°. The geometry at the S atom shows a short [1.7748?(17)?Å] S-Cbenz-yl and a long [1.8820?(15)?Å] S-Ctrit-yl bond and the C-S-C angle is 108.40?(7)°. N-C bond lengths around the azane N atom are in the range 1.454?(2)-1.463?(2)?Å. he crystal packing exhibts two rather 'non-classical' C-H?O hydrogen bonds that result in stacking of the molecules along the a as well as the b axis and give rise to columnar sub-structures.

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Project description:In the title compound, C(22)H(19)ClN(2)O(2)S, the dihedral angle between the phenyl-ene ring and the phthalimide ring system is 4.4?(1)°. There is no hydrogen bonding or ?-? stacking in the crystal structure.

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2-(2-Bromo-eth-yl)isoindoline-1,3-dione.

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2-[2-(Trimethyl-silyl)eth-yl]isoindoline-1,3-dione.

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