Unknown

Dataset Information

0

Bis(?-2-tert-butyl-phenyl-imido-1:2?N:N)chlorido-2?Cl-(diethyl ether-1?O)(2?-penta-methyl-cyclo-penta-dien-yl)lithiumtantalum(V).

ABSTRACT: In the title compound, [LiTa(C(10)H(15))(C(10)H(13)N)(2)Cl(C(4)H(10)O)], the Ta(V) atom is coordinated by a ?(5)-penta-methyl-cyclo-penta-dienyl (Cp*) ligand, a chloride ion and two N-bonded 2-tert-butyl-phenyl-imide dianions. With respect to the two N atoms, the chloride ion and the centroid of the Cp* ring, the tantalum coordination geometry is approximately tetra-hedral. The lithium cation is bonded to both the 2-tert-butyl-phenyl-imide dianions and also a diethyl ether mol-ecule, in an approximate trigonal planar arrangement. The Ta?Li separation is 2.681?(15)?Å. In the crystal, a weak C-H?Cl inter-action links the mol-ecules. When compared to the 2,6-diisopropyl-phenyl-imide analogue ('the Wigley derivative') of the title compound, the two structures are conformationally matched with an overall r.m.s. difference of 0.461Å.

SUBMITTER: Cole JM 

PROVIDER: S-EPMC3120624 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis(μ-2-tert-butyl-phenyl-imido-1:2κN:N)chlorido-2κCl-(diethyl ether-1κO)(2η-penta-methyl-cyclo-penta-dien-yl)lithiumtantalum(V).

Cole Jacqueline M JM   Chan Michael C W MC   Gibson Vernon C VC   Howard Judith A K JA  

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title compound, [LiTa(C(10)H(15))(C(10)H(13)N)(2)Cl(C(4)H(10)O)], the Ta(V) atom is coordinated by a η(5)-penta-methyl-cyclo-penta-dienyl (Cp*) ligand, a chloride ion and two N-bonded 2-tert-butyl-phenyl-imide dianions. With respect to the two N atoms, the chloride ion and the centroid of the Cp* ring, the tantalum coordination geometry is approximately tetra-hedral. The lithium cation is bonded to both the 2-tert-butyl-phenyl-imide dianions and also a diethyl ether mol-ecule, in an appro  ...[more]

Similar Datasets

Unknown Di-?-iodido-bis-[(diethyl ether-?O)(?-1,3-di-tert-butyl-cyclo-penta-dien-yl)ytterbium(II)].
| S-EPMC2915154 | biostudies-literature
Unknown (tert-Butyl-imido)bis-(η-cyclo-penta-dien-yl)pyridine-zirconium(IV).
| S-EPMC3007953 | biostudies-literature
Unknown Tricarbonyl-chlorido(?(5)-cyclo-penta-dien-yl)molybdenum(II).
| S-EPMC3343786 | biostudies-literature
Unknown Crystal structure of (1,3-di-tert-butyl-?(5)-cyclo-penta-dien-yl)tri-methyl-hafnium(IV).
| S-EPMC4420044 | biostudies-literature
Unknown Bis(tetra-butyl-ammonium) [2-(eth-oxy-carbony)phenyl-imido]-?(6)-oxido-dodeca-?(2)-oxido-penta-oxidohexa-molybdenum diethyl ether hemisolvate.
| S-EPMC3393191 | biostudies-literature
Unknown (μ-Di-<i>tert</i>-butyl-silanediolato)bis-[bis-(η<sup>5</sup>-cyclo-penta-dien-yl)methyl-zirconium].
| S-EPMC6895932 | biostudies-literature
Unknown Di-?-tert-butanolato-bis-[bis-(?-cyclo-penta-dien-yl)erbium(III)].
| S-EPMC2960763 | biostudies-literature
Unknown Penta-carbonyl-2?C-chlorido-1?Cl-bis-[1(?)-cyclo-penta-dien-yl](?-?-oxido-benzyl-idene-1:2?O:C)titanium(IV)tungsten(0).
| S-EPMC2960115 | biostudies-literature
Unknown Penta-carbonyl-2?C-chlorido-1?Cl-bis-[1(?)-cyclo-penta-dien-yl](?-1-oxido-ethyl-ene-1:2?O:C)chromium(0)zirconium(IV).
| S-EPMC2968157 | biostudies-literature
Unknown Chlorido(chloro-diphenyl-phosphine-?P)(diphenyl-piperidinophosphine-?P)(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II).
| S-EPMC2977503 | biostudies-literature