Scaling Laws in Supramolecular Polymer Networks.
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ABSTRACT:
SUBMITTER: Xu D
PROVIDER: S-EPMC3135979 | biostudies-literature | 2011
REPOSITORIES: biostudies-literature
Publications
Scaling Laws in Supramolecular Polymer Networks.
Xu Donghua D Craig Stephen L SL
Macromolecules 20110101 13
The linear rheological properties of networks formed by adding bis-Pd(II) cross-linkers to poly(4-vinylpyridine) (PVP) solution are examined, and the scaling law relationships between the zero shear viscosity (η(0)) of the networks versus the concentration of PVP solution (C(PVP)), the concentration of cross-linkers (C(X)), and the number density of elastically active chains (v(phantom)) are experimentally determined. The scaling law relationships are compared to the theoretical expectations of ...[more]
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