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4-(pyridin-2-yl)thiazol-2-yl thioglycosides as bidentate ligands for oligosaccharide synthesis via temporary deactivation.

ABSTRACT: This study focusses on a new concept for oligosaccharide synthesis based on 4-(pyridin-2-yl)thiazol-2-yl thioglycosides that can either act as effective glycosyl donors or can be deactivated by stable bidentate complexation with palladium(II) bromide.

SUBMITTER: Pornsuriyasak P 

PROVIDER: S-EPMC3150469 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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4-(pyridin-2-yl)thiazol-2-yl thioglycosides as bidentate ligands for oligosaccharide synthesis via temporary deactivation.

Pornsuriyasak Papapida P   Rath Nigam P NP   Demchenko Alexei V AV  

Chemical communications (Cambridge, England) 20081001 43

This study focusses on a new concept for oligosaccharide synthesis based on 4-(pyridin-2-yl)thiazol-2-yl thioglycosides that can either act as effective glycosyl donors or can be deactivated by stable bidentate complexation with palladium(II) bromide. ...[more]

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