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Acetonitrile-dicarbon-yl(?-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluorido-borate.

ABSTRACT: In the structure of the title compound, [Fe{?(5)-C(5)(CH(3))(5)}(NCCH(3))(CO)(2)]BF(4), the arrangement of ligands around the Fe atom is in a pseudo-octa-hedral three-legged piano-stool fashion in which the penta-methyl-cyclo-penta-dienyl (Cp*) ligand occupies three apical coordination sites, while the two carbonyl and one acetonitrile ligands form the basal axes of the coordination. The Fe-N bond length is 1.924?(3)?Å and the Fe-Cp* centroid distance is 1.722?Å.

SUBMITTER: M'thiruaine CM

PROVIDER: S-EPMC3151746 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Acetonitrile-dicarbon-yl(η-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluorido-borate.

M'thiruaine Cyprian M CM Friedrich Holger B HB Changamu Evans O EO Bala Muhammad D MD

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the structure of the title compound, [Fe{η(5)-C(5)(CH(3))(5)}(NCCH(3))(CO)(2)]BF(4), the arrangement of ligands around the Fe atom is in a pseudo-octa-hedral three-legged piano-stool fashion in which the penta-methyl-cyclo-penta-dienyl (Cp*) ligand occupies three apical coordination sites, while the two carbonyl and one acetonitrile ligands form the basal axes of the coordination. The Fe-N bond length is 1.924 (3) Å and the Fe-Cp* centroid distance is 1.722 Å. ...[more]

PMID: 21836908

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