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Poly[aqua-bis-[?(2)-2-(pyridin-4-ylsulfan-yl)acetato]-zinc].

ABSTRACT: The crystal structure of the title complex, [Zn(C(7)H(6)NO(2)S)(2)(H(2)O)](n), consists of extended layers parallel to (001) with 2-(pyridin-4-ylsulfan-yl)acetate ligands bridging the Zn(II) atoms. The Zn(II) atom shows a distorted penta-gonal-bipyramidal coordination environment. The Zn(II) and one O atom are situated on a crystallographic twofold rotation axis. In the crystal, intra-layer O-H?O hydrogen-bond inter-actions help to consolidate the coordination layer.

SUBMITTER: Wang ZC

PROVIDER: S-EPMC3151789 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Poly[aqua-bis-[μ(2)-2-(pyridin-4-ylsulfan-yl)acetato]-zinc].

Wang Zhi-Chao ZC Ding Bo B Wang Xiu-Guang XG Zhao Xiao-Jun XJ

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

The crystal structure of the title complex, [Zn(C(7)H(6)NO(2)S)(2)(H(2)O)](n), consists of extended layers parallel to (001) with 2-(pyridin-4-ylsulfan-yl)acetate ligands bridging the Zn(II) atoms. The Zn(II) atom shows a distorted penta-gonal-bipyramidal coordination environment. The Zn(II) and one O atom are situated on a crystallographic twofold rotation axis. In the crystal, intra-layer O-H⋯O hydrogen-bond inter-actions help to consolidate the coordination layer. ...[more]

PMID: 21836966

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