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Bis(3-methyl-pyridine-?N)bis-(thio-cyanato-?N)zinc.

ABSTRACT: The asymmetric unit of the title compound, [Zn(NCS)(2)(C(6)H(7)N)(2)], consists of one Zn(2+) cation and two thio-cyanate anions, all situated on special positions with site symmetry .m., and one 3-methyl-pyridine ligand. The zinc cation is coordinated by four N atoms of two terminal N-bonded thio-cyanate anions and of two symmetry-related 3-methyl-pyridine co-ligands, defining a slightly distorted tetra-hedral coordination polyhedron.

SUBMITTER: Boeckmann J 

PROVIDER: S-EPMC3151950 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Bis(3-methyl-pyridine-κN)bis-(thio-cyanato-κN)zinc.

Boeckmann Jan J   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

The asymmetric unit of the title compound, [Zn(NCS)(2)(C(6)H(7)N)(2)], consists of one Zn(2+) cation and two thio-cyanate anions, all situated on special positions with site symmetry .m., and one 3-methyl-pyridine ligand. The zinc cation is coordinated by four N atoms of two terminal N-bonded thio-cyanate anions and of two symmetry-related 3-methyl-pyridine co-ligands, defining a slightly distorted tetra-hedral coordination polyhedron. ...[more]

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