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(E)-2-(4-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazinecarboxamide.

ABSTRACT: The asymmetric unit of the title compound, C(9)H(11)N(3)O(3), consists of two crystallographically independent mol-ecules. Both mol-ecules are almost planar, with r.m.s. deviations of 0.107 and 0.099 Å. In the crystal, the two independent mol-ecules form a dimer with an R(2) (2)(8) ring motif via N-H⋯O hydrogen bonds. The dimers are further linked into a three-dimensional network by O-H⋯O and N-H⋯O hydrogen bonds.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3151979 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(2E)-2-(4-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazinecarboxamide.

Project description:In the title compound, C(9)H(11)N(3)O(3), two mol-ecules are present in the asymmetric unit in which the 4-hy-droxy-3-meth-oxy-benzaldehyde and hydrazinecarboxamide units are almost planar [with r.m.s. deviations 0.0212 and 0.0066 Å, respectively, in one mol-ecule and 0.0346 and 0.0095 Å, respectively, in the other] and are oriented at dihedral angles of 9.7 (3) and 16.6 (3)°. In both mol-ecules, two S(5) ring motifs are present due to N-H⋯N and O-H⋯O hydrogen bonds. In the crystal, the mol-ecules are dimerized with each other due to pairs of N-H⋯O hydrogen bonds, forming an R(2) (2)(8) ring motif. O-H⋯O hydrogen bonds lead to the formation of a three-dimensional network.

| S-EPMC3393335 | biostudies-literature

(2E)-2-(3-Eth-oxy-2-hy-droxy-benzyl-idene)hydrazinecarboxamide.

Project description:The title compound, C10H13N3O3, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. A classical intra-molecular O-H⋯N hydrogen bond is present. The two N atoms of the hydrazinecarboxamide unit are also involved in inter-molecular N-H⋯O hydrogen bonds, with the O atom of the hydrazinecarboxamide group acting as the acceptor. Pairs of N-H⋯O hydrogen bond link the mol-ecules into centrosymmetric dimers, which are linked by further N-H⋯O hydrogen bonds into chains along the b axis. The chains are linked by C-H⋯π inter-actions.

| S-EPMC3629631 | biostudies-literature

(E)-4-Hy-droxy-N'-(3-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.

Project description:The mol-ecule of the title benzohydrazide derivative, C(15)H(14)N(2)O(4), exists in a trans conformation with respect to the C=N double bond and is twisted, the dihedral angle between the two benzene rings being 24.17?(6)°. The meth-oxy group is almost co-planar with respect to the attached benzene ring [C(m)-O-C-C (m = meth-yl) = -1.45?(17)°]. In the crystal, the mol-ecules are linked by N-H?O and O-H?O hydrogen bonds into sheets parallel to the bc plane. These sheets are further connected into a three-dimensional network by weak C-H?O and C-H?? inter-actions.

| S-EPMC3201407 | biostudies-literature

(E)-4-Hy-droxy-N'-(4-hy-droxy-3-meth-oxy-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(4), the N=C double bond has an E configuration. The two benzene rings make a dihedral angle of 28.59?(6)°. In the crystal, mol-ecules are linked into a three-dimensional network by inter-molecular N-H?O, O-H?O and C-H?O hydrogen bonds and stabilized by weak C-H?? inter-actions.

| S-EPMC3011781 | biostudies-literature

(E)-4-Hy-droxy-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(4), the dihedral angle between the benzene rings is 40.59 (4)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal, N-H⋯O, O-H⋯O and C-H⋯O inter-actions link the mol-ecules into a three-dimensional network.

| S-EPMC3394058 | biostudies-literature

N'-(4-Hy-droxy-benzyl-idene)-3-meth-oxy-benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(3), the dihedral angle between the two benzene rings is 47.9 (3)°. In the crystal, mol-ecules are linked through N-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds, forming layers parallel to the ab plane.

| S-EPMC3274989 | biostudies-literature

(E)-N'-(3-Hy-droxy-4-meth-oxy-benzyl-idene)-4-meth-oxy-benzohydrazide.

Project description:The title mol-ecule, a benzohydrazide derivative, C(16)H(16)N(2)O(4), is twisted with a dihedral angle of 69.97 (5)° between the two benzene rings. An intra-molecular O-H⋯O hydrogen bond generates an S(5) ring motif. In the crystal, mol-ecules are linked by N-H⋯O and weak C-H⋯O hydrogen bonds into a chain along the c axis. C-H⋯π inter-actions are also present.

| S-EPMC3239014 | biostudies-literature

(E)-4-Hy-droxy-N'-(2-meth-oxy-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(14)N(2)O(3), the dihedral angle between the benzene rings is 66.56?(5)°. In the crystal, N-H?O, O-H?O and C-H?O inter-actions link the mol-ecules into a three-dimensional network. A ?-? inter-action, with a centroid-centroid distance of 3.628?(6)?Å, helps to establish the packing.

| S-EPMC3379405 | biostudies-literature

2-{[2-(2-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-6-meth-oxy-phenol.

Project description:The title compound, C(16)H(16)N(2)O(4), was obtained from the reaction of hydrazine hydrate and o-vanilin in absolute ethanol. The mol-ecule is almost planar (except for the methyl H atoms), with a mean deviation from the plane of 0.0259?Å. The mol-ecular structure also exhibits an approximate non-crystallographic twofold axis. Intra-molecular O-H?N hydrogen bonds occur. In the crystal, inter-molecular C-H?O hydrogen bonds generate mol-ecular zigzag sheets. The sheets stack through C-H?? inter-actions, leading to a three-dimensional-network.

| S-EPMC3201493 | biostudies-literature

2-{[2-(2-Hy-droxy-5-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-4-meth-oxy-phenol.

Project description:The title phenyl-hydrazine derivative, C16H16N2O4, has a crystallographically imposed centre of symmetry. Except for the methyl group, all non-H atoms are almost coplanar (r.m.s. deviation = 0.0095 Å). Intra-molecular O-H⋯N hydrogen bonds are observed, generating S(6) graph-set ring motifs.

| S-EPMC3998297 | biostudies-literature

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