Ontology highlight
ABSTRACT:
SUBMITTER: Olmstead MM
PROVIDER: S-EPMC3151985 | biostudies-literature | 2011 Jul
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20110604 Pt 7
The title compound, [Mn(2)O(2)(C(10)H(24)N(4))(2)](C(24)H(20)B)(2)Cl·2CH(3)CN, is a mixed-valent Mn(III)/Mn(IV) oxide-bridged mangan-ese dimer with one chloride and two tetra-phenyl-borate counter-anions. There are two non-coordinated mol-ecules of acetonitrile in the formula unit. A center of inversion is present between the two metal atoms, and, consequently, there is no distinction between Mn(III) and Mn(IV) metal centers. In the Mn(2)O(2) core, the Mn-O distances are 1.817 (3) and 1.821 (3) ...[more]