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N'-[(E)-2-Meth-oxy-benzyl-idene]pyrazine-2-carbohydrazide.

ABSTRACT: In the title compound, C(13)H(12)N(4)O(2), all the non-H atoms lie on a crystallographic mirror plane and an intra-molecular N-H?N hydrogen bond generates an S(5) ring; the conformation about the imine bond [1.280?(3)?Å] is E. In the crystal, mol-ecules assemble into a two-dimensional array via C-H?O(carbon-yl) and C-H?N(pyrazine) contacts. Layers stack along the b-axis direction via weak ?-? inter-actions between pyrazine rings [ring centroid distance = 3.8028?(8)?Å].

SUBMITTER: de Souza MV

PROVIDER: S-EPMC3152029 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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N'-[(E)-2-Meth-oxy-benzyl-idene]pyrazine-2-carbohydrazide.

de Souza Marcus V N MV da Silva Lima Camilo H CH Wardell James L JL Wardell Solange M S V SM Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the title compound, C(13)H(12)N(4)O(2), all the non-H atoms lie on a crystallographic mirror plane and an intra-molecular N-H⋯N hydrogen bond generates an S(5) ring; the conformation about the imine bond [1.280 (3) Å] is E. In the crystal, mol-ecules assemble into a two-dimensional array via C-H⋯O(carbon-yl) and C-H⋯N(pyrazine) contacts. Layers stack along the b-axis direction via weak π-π inter-actions between pyrazine rings [ring centroid distance = 3.8028 (8) Å]. ...[more]

PMID: 21837107

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