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4-[(4-Chloro-phen-yl)diazen-yl]-3-meth-oxy-aniline.

ABSTRACT: The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20?(8)°. Inter-molecular N-H?O hydrogen bonds between the amine and meth-oxy groups lead to the formation of a chain-like polymer along the c axis with a C(6) graph set. There is also weak non-classical C-H?N hydrogen bonds involving an aromatic C-H group and a diazenyl N atom, which connect the chains into a two-dimensional framework.

SUBMITTER: Rofouei MK 

PROVIDER: S-EPMC3152038 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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4-[(4-Chloro-phen-yl)diazen-yl]-3-meth-oxy-aniline.

Rofouei Mohammad Kazem MK   Ghalami Zahra Z   Attar Gharamaleki Jafar J   Bruno Giuseppe G   Amiri Rudbari Hadi H  

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20 (8)°. Inter-molecular N-H⋯O hydrogen bonds between the amine and meth-oxy groups lead to the formation of a chain-like polymer along the c axis with a C(6) graph set. There is also weak non-classical C-H⋯N hydrogen bonds involving an aromatic C-H group and a diazenyl N atom, which connect the chains into a two-dimensional framework. ...[more]

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