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Sodium p-toluenesulfinate tetra-hydrate.

ABSTRACT: The title compound, Na(+)·C(7)H(7)O(2)S(-)·4H(2)O, is the hydrate of the sodium salt of para-toluene-sulfinic acid. The mol-ecular geometry around the sulfur atom is tetra-hedral with X-S-Y angles spanning a range of 102.23?(6)-110.04?(6)°. In the crystal, the water mol-ecules connect the sodium cations into chains along the b axis via O-H?O hydrogen bonds. An inter-molecular O-H?? inter-action is also observed.

SUBMITTER: Betz R

PROVIDER: S-EPMC3152039 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Sodium p-toluenesulfinate tetra-hydrate.

Betz Richard R Gerber Thomas T

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

The title compound, Na(+)·C(7)H(7)O(2)S(-)·4H(2)O, is the hydrate of the sodium salt of para-toluene-sulfinic acid. The mol-ecular geometry around the sulfur atom is tetra-hedral with X-S-Y angles spanning a range of 102.23 (6)-110.04 (6)°. In the crystal, the water mol-ecules connect the sodium cations into chains along the b axis via O-H⋯O hydrogen bonds. An inter-molecular O-H⋯π inter-action is also observed. ...[more]

PMID: 21836887

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