Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

3-Chloro-N'-(2-chloro-5-nitro-benzyl-idene)-benzohydrazide.

ABSTRACT: The title mol-ecule, C(14)H(9)Cl(2)N(3)O(3), has an E configuration with respect to the methyl-idene unit. The dihedral angle between the mean planes of the two benzene rings is 12.3?(3)°. In the crystal, mol-ecules are linked via bifurcated N-H?(O, N) hydrogen bonds into chains along [001].

SUBMITTER: Zhang Z

PROVIDER: S-EPMC3152110 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

3-Chloro-N'-(2-chloro-5-nitro-benzyl-idene)-benzohydrazide.

Zhang Zhen Z

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

The title mol-ecule, C(14)H(9)Cl(2)N(3)O(3), has an E configuration with respect to the methyl-idene unit. The dihedral angle between the mean planes of the two benzene rings is 12.3 (3)°. In the crystal, mol-ecules are linked via bifurcated N-H⋯(O, N) hydrogen bonds into chains along [001]. ...[more]

PMID: 21837044

Similar Datasets

N'-(2-Chloro-benzyl-idene)-4-nitro-benzohydrazide.

Project description:In the title compound, C(14)H(10)ClN(3)O(3), the dihedral angle between the benzene rings is 6.64?(13)°. In the crystal, mol-ecules are linked through N-H?O hydrogen bonds, forming chains running along the c axis direction.

| S-EPMC3275020 | biostudies-literature

4-Chloro-N'-[(Z)-4-nitro-benzyl-idene]benzohydrazide monohydrate.

Project description:In the title compound, C(14)H(10)ClN(3)O(3)·H(2)O, the benzohydrazide group is not planar and the mol-ecule exists in a cis configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 38.7?(3)°. In the crystal structure, mol-ecules are linked by O-H?O, O-H?N and N-H?O hydrogen bonds into a two-dimensional network parallel to the (100) plane. The crystal structure is further stabilized by weak C-H?O inter-actions.

| S-EPMC2960631 | biostudies-literature

2-Chloro-N'-(5-hydr-oxy-2-nitro-benzyl-idene)benzohydrazide.

Project description:The mol-ecule of the title Schiff base compound, C(14)H(10)ClN(3)O(4), exists in a trans configuration with respect to the acyclic C=N bond. The dihedral angle between the two benzene rings is 62.37?(9)°. An intra-molecular C-H?O hydrogen bond is observed. In the crystal structure, adjacent mol-ecules are linked into a ribbon along [10] by O-H?O and N-H?O hydrogen bonds.

| S-EPMC2979760 | biostudies-literature

(E)-N'-(5-Chloro-2-hydroxy-benzyl-idene)-2-nitro-benzohydrazide.

Project description:In the title Schiff base compound, C(14)H(10)ClN(3)O(4), the mol-ecule adopts an E geometry with respect to the C=N bond and an intra-molecular O-H⋯N hydrogen bond is present. The benzene rings form a dihedral angle of 73.4 (2)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.

| S-EPMC2970017 | biostudies-literature

(E)-N'-(2-Chloro-5-nitro-benzyl-idene)-4-methoxy-benzohydrazide.

Project description:In the title compound, C(15)H(12)ClN(3)O(4), the benzohydrazide group is not planar and the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 0.4 (3)°. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming chains parallel to the c axis.

| S-EPMC2959696 | biostudies-literature

N'-(2-Chloro-5-nitro-benzyl-idene)-3-hydroxy-benzohydrazide methanol solvate.

Project description:In the title compound, C(14)H(10)ClN(3)O(4)·CH(3)OH, the dihedral angle between the two benzene rings is 33.9 (2)°. In the crystal structure, the methanol solvent mol-ecules are linked to the Schiff base mol-ecules through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds. Mol-ecules are further linked through inter-molecular O-H⋯O and O-H⋯N hydrogen bonds, forming chains running along the b axis.

| S-EPMC2962016 | biostudies-literature

3-Chloro-N'-(4-hy-droxy-3-nitro-benzyl-idene)benzohydrazide methanol disolvate.

Project description:In the title compound, C(14)H(10)ClN(3)O(4)·2CH(4)O, the main mol-ecule is in an E configuration with respect to the methyl-idene unit. The dihedral angle between the mean planes of the two benzene rings is 1.9?(3)°. In the crystal, inter-molecular N-H?O, O-H?O and bifurcated O-H?(O, O) hydrogen bonds link the components into sheets parallel to (100). An intra-molecular O-H?O hydrogen bond is also present.

| S-EPMC3151852 | biostudies-literature

N'-(2-Hydr-oxy-5-chloro-benzyl-idene)-4-nitro-benzohydrazide methanol solvate.

Project description:The title compound, C(14)H(10)ClN(3)O(4)·CH(4)O, was synthesized from the reaction of 5-chloro-salicylaldehyde with 4-nitro-benzohydrazide in methanol. The Schiff base mol-ecule is nearly planar, with a dihedral angle of 9.1?(3)° between the two benzene rings. The methanol solvent mol-ecules are linked to the Schiff base mol-ecules by N-H?O, O-H?N and O-H?O hydrogen bonds, forming chains running parallel to the a axis.

| S-EPMC2961199 | biostudies-literature

3-Chloro-N'-(2-chloro-benzyl-idene)benzohydrazide.

Project description:The title compound, C(14)H(10)Cl(2)N(2)O, was prepared from the reaction of 2-chloro-benzaldehyde with 3-chloro-benzo-hydrazide in methanol. The mol-ecule adopts an E configuration about the methyl-idene unit and the two aromatic rings form a dihedral angle of 13.8 (2)°. In the crystal, mol-ecules are linked via inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, forming chains along the c axis.

| S-EPMC3051651 | biostudies-literature

2-Chloro-N'-(2-chloro-benzyl-idene)benzohydrazide.

Project description:The mol-ecule of the title compound, C(14)H(10)Cl(2)N(2)O, adopts an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 79.7 (2)°. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O, C-H⋯Cl and C-H⋯O hydrogen bonds, forming chains running along the b axis.

| S-EPMC2970987 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data