Ontology highlight
ABSTRACT:
SUBMITTER: Abbaraju S
PROVIDER: S-EPMC3171176 | biostudies-literature | 2011 Sep
REPOSITORIES: biostudies-literature
Abbaraju Santhi S Bhanushali Mayur M Zhao Cong-Gui CG
Tetrahedron 20110901 39
An efficient method for enantioselective synthesis of β-nitrophosphonates via the Michael addition of diphenyl phosphite to nitroalkenes using the readily available quinidine thiourea organocatalyst has been developed. The desired β-nitrophosphonates were obtained in good ee values. Molecular sieves were found to be crucial for achieving high reproducible yields in this reaction. ...[more]