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Catena-Poly[[bis-(N,N-dimethyl-formamide-?O)zinc]-?(2)-oxalato-?O,O:O,O].

ABSTRACT: In the crystal structure of the title compound, [Zn(C(2)O(4))(C(3)H(7)NO)(2)](n), the Zn(II) ion is situated on a twofold rotation axis and has a distorted octa-hedral coordination geometry defined by the O atoms of two dimethyl-formamide mol-ecules and four O atoms of two bidentate oxalate ligands. The oxalate anion is located on an inversion centre and bridges two metal ions, resulting in a polymeric structure with infinite zigzag chains extending parallel to [010].

SUBMITTER: Lee JE

PROVIDER: S-EPMC3200650 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(N,N-dimethyl-formamide-κO)zinc]-μ(2)-oxalato-κO,O:O,O].

Lee Ju Eun JE Lee Hong-In HI

Acta crystallographica. Section E, Structure reports online 20110802 Pt 9

In the crystal structure of the title compound, [Zn(C(2)O(4))(C(3)H(7)NO)(2)](n), the Zn(II) ion is situated on a twofold rotation axis and has a distorted octa-hedral coordination geometry defined by the O atoms of two dimethyl-formamide mol-ecules and four O atoms of two bidentate oxalate ligands. The oxalate anion is located on an inversion centre and bridges two metal ions, resulting in a polymeric structure with infinite zigzag chains extending parallel to [010]. ...[more]

PMID: 22058834

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