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Chlorido(10,11,12,13-tetra-hydro-4,5,9,14-tetra-aza-benzo[b]triphenyl-ene-?N,N)copper(I).

ABSTRACT: The Cu(I) atom in the title compound, [CuCl(C(18)H(14)N(4))], is N,N'-chelated by the N-heterocyclic ligand and coordinated by one Cl(-) anion in a distorted trigonal geometry. In the crystal, the Cu(I) atom is disordered over two positions in a 0.667?(6):0.333?(6) ratio. The deviation of the Cu atom from the N/N/Cl coordination plane is 0.013?(3)?Å for the major component and 0.073?(6)?Å for the minor component. Two methyl-ene C atoms are also disordered over two positions in a 0.667?(6):0.333?(6) ratio.

SUBMITTER: Hong J

PROVIDER: S-EPMC3200675 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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Chlorido(10,11,12,13-tetra-hydro-4,5,9,14-tetra-aza-benzo[b]triphenyl-ene-κN,N)copper(I).

Hong Jun J Li Xiu-Ying XY Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110831 Pt 9

The Cu(I) atom in the title compound, [CuCl(C(18)H(14)N(4))], is N,N'-chelated by the N-heterocyclic ligand and coordinated by one Cl(-) anion in a distorted trigonal geometry. In the crystal, the Cu(I) atom is disordered over two positions in a 0.667 (6):0.333 (6) ratio. The deviation of the Cu atom from the N/N/Cl coordination plane is 0.013 (3) Å for the major component and 0.073 (6) Å for the minor component. Two methyl-ene C atoms are also disordered over two positions in a 0.667 (6):0.333 ...[more]

PMID: 22065705

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