Diacetato-κO;κO,O'-aqua-(2,4,6-tri-2-pyridyl-1,3,5-triazine-κN,N,N)manganese(II) monohydrate.

ABSTRACT: The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta-gonal-bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water mol-ecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water mol-ecules are linked by inter- and intra-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds into a three-dimensional network.

SUBMITTER: Ha K 

PROVIDER: S-EPMC3200744 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature