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2-(1,3-Benzothia-zol-2-yl)-6-eth-oxy-phenol.

ABSTRACT: In the title compound, C(15)H(13)NO(2)S, the benzothia-zole unit is essentially planar [maximum deviation = -0.0099?(5)?Å for the S atom] and is oriented at a dihedral angle of 4.8?(5)° with respect to the benzene ring. An intra-molecular O-H?N hydrogen bond generates an S(6) ring motif. The crystal packing is stabilized by C-H?? inter-actions.

SUBMITTER: Lakshmanan D

PROVIDER: S-EPMC3200763 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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2-(1,3-Benzothia-zol-2-yl)-6-eth-oxy-phenol.

Lakshmanan D D Raj R Madhan RM Selvakumar R R Bakthadoss M M Murugavel S S

Acta crystallographica. Section E, Structure reports online 20110806 Pt 9

In the title compound, C(15)H(13)NO(2)S, the benzothia-zole unit is essentially planar [maximum deviation = -0.0099 (5) Å for the S atom] and is oriented at a dihedral angle of 4.8 (5)° with respect to the benzene ring. An intra-molecular O-H⋯N hydrogen bond generates an S(6) ring motif. The crystal packing is stabilized by C-H⋯π inter-actions. ...[more]

PMID: 22058918

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An ortho-rhom-bic polymorph of 2-(1,3-benzothia-zol-2-yl)-6-eth-oxy-phenol.

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A monoclinic modification of 2-[(1,3-benzothia-zol-2-yl)imino-meth-yl]phenol.

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Project description:The mol-ecule of the title compound, C(30)H(24)N(2)O(2)S(4), adopts a Z-shaped conformation. The terminal benzothia-zole ring systems are oriented at a dihedral angle of 60.81 (8)°, while the central benzene rings are twisted to each other by a dihedral angle of 13.56 (14)°. Weak inter-molecular C-H⋯π inter-actions are present in the crystal structure.

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