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Bis[3,5-difluoro-2-(4-methyl-pyridin-2-yl)phenyl-?C,N](picolinato-?N,O)iridium(III) chloro-form monosolvate.

ABSTRACT: In the title complex, [Ir(C(12)H(8)F(2)N)(2)(C(6)H(4)NO(2))]·CHCl(3), two similar mol-ecules of each component comprise the asymmetric unit. The independent complex mol-ecules are linked by inter-molecular ?-? inter-actions [centroid-centroid distance = 3.830?(4)?Å]. The Ir(III) ion adopts a distorted octa-hedral geometry, being coordinated by three N atoms, two C atoms, and one O atom of three bidentate ligands, with the N atoms arranged meridionally.

SUBMITTER: Kim YI 

PROVIDER: S-EPMC3200786 | biostudies-literature |

REPOSITORIES: biostudies-literature

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