Unknown

Dataset Information

0

3-Amino-1-methyl-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.

ABSTRACT: The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent mol-ecules, which are non-planar as they are buckled owing to the ethyl-ene portion. The dihedral angle between the benzene rings is 26.4?(1)° in one mol-ecule and 32.9?(1)° in the other. In the crystal, the mol-ecules are disposed about a false inversion center, and are linked by two N-H?N hydrogen bonds, generating a dimer. The dimers are linked by further N-H?N hydrogen bonds, resulting in a chain that runs along the longest axis of the ortho-rhom-bic unit cell.

SUBMITTER: Al-Youbi AO 

PROVIDER: S-EPMC3201274 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

3-Amino-1-methyl-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.

Al-Youbi Abdulrahman O AO   Asiri Abdullah M AM   Faidallah Hassan M HM   Alamry Khalid A KA   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

The asymmetric unit of the title compound, C(17)H(13)N(3), contains two independent mol-ecules, which are non-planar as they are buckled owing to the ethyl-ene portion. The dihedral angle between the benzene rings is 26.4 (1)° in one mol-ecule and 32.9 (1)° in the other. In the crystal, the mol-ecules are disposed about a false inversion center, and are linked by two N-H⋯N hydrogen bonds, generating a dimer. The dimers are linked by further N-H⋯N hydrogen bonds, resulting in a chain that runs al  ...[more]

Similar Datasets

Unknown 3-Amino-1-(4-bromo-phen-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.
| S-EPMC3201339 | biostudies-literature
Unknown 3-Amino-1-(thio-phen-2-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.
| S-EPMC3343991 | biostudies-literature
Unknown 3-Amino-1-(3,4-dimeth-oxy-phen-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.
| S-EPMC3344065 | biostudies-literature
Unknown 3-Amino-1-(2H-1,3-benzodioxol-5-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.
| S-EPMC3200934 | biostudies-literature
Unknown 3-Amino-1-(4-meth-oxy-phen-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.
| S-EPMC3200821 | biostudies-other
Unknown 2-Amino-4-phenyl-5,6-dihydro-benzo[h]quinoline-3-carbonitrile-3-amino-1-phenyl-9,10-dihydro-phenanthrene-2,4-dicarbonitrile (5/3).
| S-EPMC3247607 | biostudies-literature
Unknown A second monoclinic polymorph for 3-amino-1-(4-meth-oxy-phen-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile.
| S-EPMC3344100 | biostudies-literature
Unknown 2-Amino-4-(4-chloro-phen-yl)-5,6-dihydro-benzo[h]quinoline-3-carbonitrile-3-amino-1-(4-chloro-phen-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile (1/4).
| S-EPMC3247609 | biostudies-literature
Unknown 2-Amino-4-(3,4-dimeth-oxy-phen-yl)-5,6-dihydro-benzo[h]quinoline-3-carbo-nitrile-3-amino-1-(3,4-dimeth-oxy-phen-yl)-9,10-dihydro-phenanthrene-2,4-dicarbonitrile (1/19).
| S-EPMC3247608 | biostudies-literature
Unknown 6-[3-(2,4-Dimethyl-anilino)-2-hydroxy-prop-oxy]-1,8-dihydr-oxy-3-methyl-9,10-dihydro-anthracene-9,10-dione.
| S-EPMC2968285 | biostudies-literature