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Cyclo-hex-yl(meth-yl)ammonium {bis-[cyclo-hex-yl(meth-yl)amino]-phosphor-yl}(4-methyl-phenyl-sulfon-yl)aza-nide.

ABSTRACT: In the anion of the title salt, C(7)H(16)N(+)·C(21)H(35)N(3)O(3)PS(-), the P and S atoms are both in distorted tetra-hedral environments and the angles at the tertiary N atoms confirm their sp(2) character. The two S=O groups are in syn and gauche conformations with respect to the phosphoryl group. In the crystal, N-H?O(=S) and N-H?O(=P) hydrogen bonds involving two anions and two cations form a centrosymmetric four-component cluster.

SUBMITTER: Pourayoubi M

PROVIDER: S-EPMC3201332 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Cyclo-hex-yl(meth-yl)ammonium {bis-[cyclo-hex-yl(meth-yl)amino]-phosphor-yl}(4-methyl-phenyl-sulfon-yl)aza-nide.

Pourayoubi Mehrdad M Fadaei Hassan H Tarahhomi Atekeh A Parvez Masood M

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the anion of the title salt, C(7)H(16)N(+)·C(21)H(35)N(3)O(3)PS(-), the P and S atoms are both in distorted tetra-hedral environments and the angles at the tertiary N atoms confirm their sp(2) character. The two S=O groups are in syn and gauche conformations with respect to the phosphoryl group. In the crystal, N-H⋯O(=S) and N-H⋯O(=P) hydrogen bonds involving two anions and two cations form a centrosymmetric four-component cluster. ...[more]

PMID: 22065725

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