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2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra-fluoro-borate.

ABSTRACT: In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (-), centrosymmetrically related cations undergo base pairing via a pair of N-H?N hydrogen bonds, forming an R(2) (2)(8) ring motif. The cations and anions inter-act via N-H?F hydrogen bonds, generating supra-molecular layers parallel to ([Formula: see text]20), which are in turn linked into a three-dimensional network, forming rings of R(6) (6)(24) graph-set motif. The crystal structure is further stabilized by ?-? stacking inter-actions [centroid-centroid distance = 3.3361?(12)?Å].

SUBMITTER: Gomathi S

PROVIDER: S-EPMC3201368 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra-fluoro-borate.

Gomathi Sundaramoorthy S Muthiah Packianathan Thomas PT

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (-), centrosymmetrically related cations undergo base pairing via a pair of N-H⋯N hydrogen bonds, forming an R(2) (2)(8) ring motif. The cations and anions inter-act via N-H⋯F hydrogen bonds, generating supra-molecular layers parallel to ([Formula: see text]20), which are in turn linked into a three-dimensional network, forming rings of R(6) (6)(24) graph-set motif. The crystal structure is further stabilized by π-π stacking inte ...[more]

PMID: 22058813

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