Hydrogen-bond inter-actions in morpholinium bromide.

ABSTRACT: In the title compound, C(4)H(10)NO(+)·Br(-), which was synthesized by dehydration of diethano-lamine with HBr, morpholinium and bromide ions are linked into chains by N-H?Br hydrogen bonds describing a C(2) (1)(4) graph-set motif. Weaker bifurcated N-H?Br inter-actions join centrosymmetrically related chains through alternating binary graph-set R(4) (2)(8) and R(2) (2)(4) motifs, to form ladders along [100]. In addition, C-H?O inter-actions between centrosymmetric morpholinium cations link ladders, via[Formula: see text](8) motifs, to yield sheets parallel to (101), which in turn are crosslinked by weak C-H?O inter-actions, related across a glide plane, to form a three-dimensional network.

SUBMITTER: Padayachy K 

PROVIDER: S-EPMC3201370 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature