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Diaqua-bis-(5-methyl-pyrazine-2-carboxyl-ato-?N,O)cobalt(II) dihydrate.


ABSTRACT: In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa-hedral, with two N atoms and two O atoms from two 5-methyl-pyrazine-2-carboxyl-ate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water mol-ecules. In addition, there are two uncoordinated water mol-ecules in the asymmetric unit. The crystal structure is stabilized by a network of O-H?O and O-H?N hydrogen-bonding inter-actions, forming a three-dimensional structure.

SUBMITTER: Shi QY 

PROVIDER: S-EPMC3201376 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Diaqua-bis-(5-methyl-pyrazine-2-carboxyl-ato-κN,O)cobalt(II) dihydrate.

Shi Qi-Ying QY   Zhang Guo-Chun GC   Zhou Chun-Sheng CS   Yang Qi Q  

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10


In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa-hedral, with two N atoms and two O atoms from two 5-methyl-pyrazine-2-carboxyl-ate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water mol-ecules. In addition, there are two uncoordinated water mol-ecules in the asymmetric unit. The crystal structure is stabilized by a network of O-H⋯O and O-H⋯N hydrogen-bonding inter-actio  ...[more]

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