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N,N'-Bis(2-methyl-phen-yl)-N''-(2,2,2-trichloro-acet-yl)phospho-ric triamide.

ABSTRACT: In the title compound, C(16)H(17)Cl(3)N(3)O(2)P, the P-N bonds in the P(O)[NH(2-CH(3))C(6)H(4)](2) unit [1.623?(4) and 1.637?(3)?Å] are shorter than the P-N bond in the C(O)NHP(O) fragment [1.704?(3)?Å]. The phosphoryl and carbonyl groups are anti with respect to each other and the P atom has a distorted tetra-hedral configuration. In the crystal, adjacent mol-ecules are linked via N-H?O(P) and N-H?O(C) hydrogen bonds into an extended chain parallel to [101].

SUBMITTER: Pourayoubi M

PROVIDER: S-EPMC3201409 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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N,N'-Bis(2-methyl-phen-yl)-N''-(2,2,2-trichloro-acet-yl)phospho-ric triamide.

Pourayoubi Mehrdad M Keikha Mojtaba M Parvez Masood M

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title compound, C(16)H(17)Cl(3)N(3)O(2)P, the P-N bonds in the P(O)[NH(2-CH(3))C(6)H(4)](2) unit [1.623 (4) and 1.637 (3) Å] are shorter than the P-N bond in the C(O)NHP(O) fragment [1.704 (3) Å]. The phosphoryl and carbonyl groups are anti with respect to each other and the P atom has a distorted tetra-hedral configuration. In the crystal, adjacent mol-ecules are linked via N-H⋯O(P) and N-H⋯O(C) hydrogen bonds into an extended chain parallel to [101]. ...[more]

PMID: 22064803

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