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2-{[2-(2-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-6-meth-oxy-phenol.

ABSTRACT: The title compound, C(16)H(16)N(2)O(4), was obtained from the reaction of hydrazine hydrate and o-vanilin in absolute ethanol. The mol-ecule is almost planar (except for the methyl H atoms), with a mean deviation from the plane of 0.0259?Å. The mol-ecular structure also exhibits an approximate non-crystallographic twofold axis. Intra-molecular O-H?N hydrogen bonds occur. In the crystal, inter-molecular C-H?O hydrogen bonds generate mol-ecular zigzag sheets. The sheets stack through C-H?? inter-actions, leading to a three-dimensional-network.

SUBMITTER: Lu R

PROVIDER: S-EPMC3201493 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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2-{[2-(2-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-6-meth-oxy-phenol.

Lu Rong R Wang Wenxia W Lü Xingqiang X Zhao Shunsheng S

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

The title compound, C(16)H(16)N(2)O(4), was obtained from the reaction of hydrazine hydrate and o-vanilin in absolute ethanol. The mol-ecule is almost planar (except for the methyl H atoms), with a mean deviation from the plane of 0.0259 Å. The mol-ecular structure also exhibits an approximate non-crystallographic twofold axis. Intra-molecular O-H⋯N hydrogen bonds occur. In the crystal, inter-molecular C-H⋯O hydrogen bonds generate mol-ecular zigzag sheets. The sheets stack through C-H⋯π inter-a ...[more]

PMID: 22064826

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