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Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato-?N,O}nickel(II).

ABSTRACT: In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluoro-phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex mol-ecules are linked via inter-molecular C-H?F hydrogen bonds, forming chains along [001].

SUBMITTER: Bahron H

PROVIDER: S-EPMC3212107 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato-κN,O}nickel(II).

Bahron Hadariah H Tajuddin Amalina Mohd AM Ibrahim Wan Nazihah Wan WN Hemamalini Madhukar M Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20110702 Pt 8

In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetra-coordinated by two N atoms and two O atoms from two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluoro-phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex mol-ec ...[more]

PMID: 22090809

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Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato}palladium(II).

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Crystal structure of bis-{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-?(2) N,O}nickel(II).

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Bis{2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolato-κ(2)N,O(1)}nickel(II).

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Bis[2-(3-cyano-phenyl-imino-meth-yl)phenolato]nickel(II).

Project description:In the title complex, [Ni(C(14)H(9)N(2)O)(2)], the Ni(II) atom lies on an inversion center and is coordinated by the O atom and an N atom of two Schiff base 2-(3-cyano-phenyl-imino-meth-yl)phenolate ligands in a square-planar geometry. The dihedral angle between the cyano-phenyl and phenolate rings is 47.62?(7)°.

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Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-κ(2)N,O}cobalt(II).

Project description:The complete mol-ecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetra-hedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the planes of the aromatic rings within each ligand is 84.1 (6)°.

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cis-Bis{(E)-2-[(2-fluoro-phen-yl)imino-meth-yl]phenolato-?(2) N,O}bis-(pyridine-?N)nickel(II).

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