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1,2-Dimethyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocuprate(II).

ABSTRACT: In the title compound, (C(8)H(18)N(2))[CuCl(4)], torsion angles on the ethyl-ene bridges of the 1,4-diazo-niabicyclo-[2.2.2]octane fragment are in the range 11.9?(5)-15.0?(5)° and the [CuCl(4)](2-) anion has a strongly distorted tetra-hedral geometry. The cation is connected to the anion via three-center N-H?Cl hydrogen bonds.

SUBMITTER: Rong T

PROVIDER: S-EPMC3212112 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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1,2-Dimethyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocuprate(II).

Rong Tao T

Acta crystallographica. Section E, Structure reports online 20110702 Pt 8

In the title compound, (C(8)H(18)N(2))[CuCl(4)], torsion angles on the ethyl-ene bridges of the 1,4-diazo-niabicyclo-[2.2.2]octane fragment are in the range 11.9 (5)-15.0 (5)° and the [CuCl(4)](2-) anion has a strongly distorted tetra-hedral geometry. The cation is connected to the anion via three-center N-H⋯Cl hydrogen bonds. ...[more]

PMID: 22090814

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